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Interfacial electron transfer of cyt...

Yue, Hongjun.

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Interfacial electron transfer of cytochrome c and conjugated polyelectrolyte/surfactant complexes.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Interfacial electron transfer of cytochrome c and conjugated polyelectrolyte/surfactant complexes./
作者:	Yue, Hongjun.
面頁冊數:	235 p.
附註:	Source: Dissertation Abstracts International, Volume: 68-09, Section: B, page: 5982.
Contained By:	Dissertation Abstracts International68-09B.
標題:	Biophysics, General. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3284650
ISBN:	9780549261018

Interfacial electron transfer of cytochrome c and conjugated polyelectrolyte/surfactant complexes.
Yue, Hongjun.

Interfacial electron transfer of cytochrome c and conjugated polyelectrolyte/surfactant complexes. - 235 p.

Source: Dissertation Abstracts International, Volume: 68-09, Section: B, page: 5982.

Thesis (Ph.D.)--University of Pittsburgh, 2007.

Cytochrome c (cyt c) acts as an electron shuttle in biological respiration and photosynthesis. Although the understanding of this protein and its electron transfer (ET) reaction is relatively highly developed, many of its aspects remain unclear. We use supramolecular assemblies of cytochrome c to understand its ET at an interface in terms of how the ET depends on solution composition, SAM composition, temperature, immobilization methods and the nature of the electron tunneling pathway. From these studies we have learned: (1) the formal potential and the surface charge of cytochrome c are modified when binding to a negatively charged surface; (2) cytochrome c molecules assume a wide distribution of geometries when electrostatically binding to a negatively charged surface, which leads to a wide distribution of ET rate constants; (3) when the protein is within 14 A of the electrode, the ET rate is controlled by local frictional motions rather than by electron tunneling; (4) the binding-inactive sites, the diluent molecules on the SAM can provide alternative electron tunneling pathways from electrode surface to the heme of cytochrome c, and in suitable conditions the diluent molecules dominate in the electron tunneling pathway.

ISBN: 9780549261018Subjects--Topical Terms:

1019105
Biophysics, General.

Interfacial electron transfer of cytochrome c and conjugated polyelectrolyte/surfactant complexes.
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245 1 0 $a Interfacial electron transfer of cytochrome c and conjugated polyelectrolyte/surfactant complexes.
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500 $a Source: Dissertation Abstracts International, Volume: 68-09, Section: B, page: 5982.
502 $a Thesis (Ph.D.)--University of Pittsburgh, 2007.
520 $a Cytochrome c (cyt c) acts as an electron shuttle in biological respiration and photosynthesis. Although the understanding of this protein and its electron transfer (ET) reaction is relatively highly developed, many of its aspects remain unclear. We use supramolecular assemblies of cytochrome c to understand its ET at an interface in terms of how the ET depends on solution composition, SAM composition, temperature, immobilization methods and the nature of the electron tunneling pathway. From these studies we have learned: (1) the formal potential and the surface charge of cytochrome c are modified when binding to a negatively charged surface; (2) cytochrome c molecules assume a wide distribution of geometries when electrostatically binding to a negatively charged surface, which leads to a wide distribution of ET rate constants; (3) when the protein is within 14 A of the electrode, the ET rate is controlled by local frictional motions rather than by electron tunneling; (4) the binding-inactive sites, the diluent molecules on the SAM can provide alternative electron tunneling pathways from electrode surface to the heme of cytochrome c, and in suitable conditions the diluent molecules dominate in the electron tunneling pathway.
520 $a Poly (phenylethynylene) (PPE) based conjugated polyelectrolytes are a class of polyions having rigid backbones. We present a fluorescence correlation spectroscopy (FCS) study on the hydrodynamic properties of complexes formed by two PPE-SO3- polymers, having different charge density, with octadecyl trimethylammoniumbromide (OTAB) below the critical micelle concentration. The concentration ratio COTAB/Cmonomer ranges from 0.2 to 1800. The hydrodynamic radius of the complexes as a function of OTAB concentration has three regimes. In the low concentration regime, the complex has a comparable size with the polymer in deionized water. In the intermediate concentration regime the complexes have the largest size and substantial heterogeneity. In the high concentration regime, the complexes have a size that is about three times larger than that in the low concentration regime. The results significantly extend the understanding of the interaction between polyelectrolyte and ionic surfactant, and indicate that the rigidity of polymer backbone and COTAB/Cmonomer concentration ratio act to determine the composition of polyelectrolyte/surfactant complexes.
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