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Bio-inspired nanoscale materials: D...

Venkataraman, Shrinivas.

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Bio-inspired nanoscale materials: Design, synthesis and self-assembly behaviors of functional amphiphilic block copolymers and their impact on ionic crystal growth.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Bio-inspired nanoscale materials: Design, synthesis and self-assembly behaviors of functional amphiphilic block copolymers and their impact on ionic crystal growth./
Author:	Venkataraman, Shrinivas.
Description:	163 p.
Notes:	Adviser: Karen L. Wooley.
Contained By:	Dissertation Abstracts International68-09B.
Subject:	Chemistry, Organic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3282450
ISBN:	9780549249689

Bio-inspired nanoscale materials: Design, synthesis and self-assembly behaviors of functional amphiphilic block copolymers and their impact on ionic crystal growth.
Venkataraman, Shrinivas.

Bio-inspired nanoscale materials: Design, synthesis and self-assembly behaviors of functional amphiphilic block copolymers and their impact on ionic crystal growth. - 163 p.

Adviser: Karen L. Wooley.

Thesis (Ph.D.)--Washington University in St. Louis, 2007.

Amphiphilic compositions of biological materials are key to their complex functions. Inspired by these materials and based on their structure-property relationships, the design, synthesis and characterization of functional synthetic macromolecules were conducted via controlled radical polymerization methodologies, such as reversible addition-fragmentation chain transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP). Emphasis was placed on the development of facile synthetic methodologies to allow for the incorporation of regioselective physico-chemical functionalities in multi-block copolymers. Self-assembly behaviors of such block copolymers in bulk, aqueous and non-aqueous conditions and also the thermo-responsive properties of block copolymers containing semicrystalline domains were evaluated. The ability of those nanostructures to exert influence on bio-mimetic calcium carbonate mineralization was investigated. These results have provided better comprehension of the properties of nanostructures resulting from amphiphilic multi-block copolymers and their interactions with ionic molecular and macromolecular species in condensed heterogeneous aggregates.

ISBN: 9780549249689Subjects--Topical Terms:

516206
Chemistry, Organic.

Bio-inspired nanoscale materials: Design, synthesis and self-assembly behaviors of functional amphiphilic block copolymers and their impact on ionic crystal growth.
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520 $a Amphiphilic compositions of biological materials are key to their complex functions. Inspired by these materials and based on their structure-property relationships, the design, synthesis and characterization of functional synthetic macromolecules were conducted via controlled radical polymerization methodologies, such as reversible addition-fragmentation chain transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP). Emphasis was placed on the development of facile synthetic methodologies to allow for the incorporation of regioselective physico-chemical functionalities in multi-block copolymers. Self-assembly behaviors of such block copolymers in bulk, aqueous and non-aqueous conditions and also the thermo-responsive properties of block copolymers containing semicrystalline domains were evaluated. The ability of those nanostructures to exert influence on bio-mimetic calcium carbonate mineralization was investigated. These results have provided better comprehension of the properties of nanostructures resulting from amphiphilic multi-block copolymers and their interactions with ionic molecular and macromolecular species in condensed heterogeneous aggregates.
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