語系:
繁體中文
English
說明(常見問題)
回圖書館首頁
手機版館藏查詢
登入
回首頁
切換:
標籤
|
MARC模式
|
ISBD
Kinetic and mechanistic studies of a...
~
Purdue University., Agricultural and Biological Engineering.
FindBook
Google Book
Amazon
博客來
Kinetic and mechanistic studies of a biomimetic catalyst for hemicellulosic biomass hydrolysis.
紀錄類型:
書目-語言資料,印刷品 : Monograph/item
正題名/作者:
Kinetic and mechanistic studies of a biomimetic catalyst for hemicellulosic biomass hydrolysis./
作者:
Lu, Yulin.
面頁冊數:
152 p.
附註:
Adviser: Nathan S. Mosier.
Contained By:
Dissertation Abstracts International70-01B.
標題:
Energy. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoeng/servlet/advanced?query=3344068
Kinetic and mechanistic studies of a biomimetic catalyst for hemicellulosic biomass hydrolysis.
Lu, Yulin.
Kinetic and mechanistic studies of a biomimetic catalyst for hemicellulosic biomass hydrolysis.
- 152 p.
Adviser: Nathan S. Mosier.
Thesis (Ph.D.)--Purdue University, 2008.
The use of cellulosic biomass for fuels is limited by unavailability of a cost-effective catalytic platform to convert the feedstock into fermentable sugars. In this study, a biomimetic catalysis concept was proposed. Biomimetic catalysts are a series of dicarboxylic acids with varying chain length that structurally mimicking enzyme active site. Initial screening determined that maleic acid is superior to others with improved sugar yield. When applied to hemicellulosic biomass hydrolysis reaction, optimal condition with maleic acid catalysis resulted in over 90% of xylose yield, compared to only of 70% xylose yield by sulfuric acid catalysis. A kinetic modeling analysis of the reaction suggests that the hydrolysis reaction is higher than 1st-order kinetics, indicating that undissociated form of maleic acid may involve in the catalysis. Low severity reaction conditions are also suggested to be more favorable for hydrolysis versus degradation. However, biphasic hydrolysis pattern becomes apparent at low severity conditions. Xylose degradation pH-rate profile was examined, and transition from acid-controlled to solvent-controlled to base-catalyzed type kinetics were observed in pH 0.5 -- 7.0. Under pH 2.2 condition the xylose degradation rate was minimal. Further mechanistic study indicates that an inverse general acid catalysis mechanism is employed by maleic acid for xylose degradation reaction, and this may be associated with the existence of a very-strong short H-bond that is unique to maleic acid.Subjects--Topical Terms:
876794
Energy.
Kinetic and mechanistic studies of a biomimetic catalyst for hemicellulosic biomass hydrolysis.
LDR
:02570nam 2200313 a 45
001
858287
005
20100712
008
100712s2008 ||||||||||||||||| ||eng d
035
$a
(UMI)AAI3344068
035
$a
AAI3344068
040
$a
UMI
$c
UMI
100
1
$a
Lu, Yulin.
$3
1025336
245
1 0
$a
Kinetic and mechanistic studies of a biomimetic catalyst for hemicellulosic biomass hydrolysis.
300
$a
152 p.
500
$a
Adviser: Nathan S. Mosier.
500
$a
Source: Dissertation Abstracts International, Volume: 70-01, Section: B, page: 0442.
502
$a
Thesis (Ph.D.)--Purdue University, 2008.
520
$a
The use of cellulosic biomass for fuels is limited by unavailability of a cost-effective catalytic platform to convert the feedstock into fermentable sugars. In this study, a biomimetic catalysis concept was proposed. Biomimetic catalysts are a series of dicarboxylic acids with varying chain length that structurally mimicking enzyme active site. Initial screening determined that maleic acid is superior to others with improved sugar yield. When applied to hemicellulosic biomass hydrolysis reaction, optimal condition with maleic acid catalysis resulted in over 90% of xylose yield, compared to only of 70% xylose yield by sulfuric acid catalysis. A kinetic modeling analysis of the reaction suggests that the hydrolysis reaction is higher than 1st-order kinetics, indicating that undissociated form of maleic acid may involve in the catalysis. Low severity reaction conditions are also suggested to be more favorable for hydrolysis versus degradation. However, biphasic hydrolysis pattern becomes apparent at low severity conditions. Xylose degradation pH-rate profile was examined, and transition from acid-controlled to solvent-controlled to base-catalyzed type kinetics were observed in pH 0.5 -- 7.0. Under pH 2.2 condition the xylose degradation rate was minimal. Further mechanistic study indicates that an inverse general acid catalysis mechanism is employed by maleic acid for xylose degradation reaction, and this may be associated with the existence of a very-strong short H-bond that is unique to maleic acid.
590
$a
School code: 0183.
650
4
$a
Energy.
$3
876794
650
4
$a
Engineering, Agricultural.
$3
1019504
650
4
$a
Engineering, Chemical.
$3
1018531
690
$a
0539
690
$a
0542
690
$a
0791
710
2
$a
Purdue University.
$b
Agricultural and Biological Engineering.
$3
1025335
773
0
$t
Dissertation Abstracts International
$g
70-01B.
790
$a
0183
790
1 0
$a
Hillhouse, Hugh W.
$e
committee member
790
1 0
$a
Ladisch, Michael R.
$e
committee member
790
1 0
$a
Mosier, Nathan S.,
$e
advisor
790
1 0
$a
Ribeiro, Fabio H.
$e
committee member
791
$a
Ph.D.
792
$a
2008
856
4 0
$u
http://pqdd.sinica.edu.tw/twdaoeng/servlet/advanced?query=3344068
筆 0 讀者評論
館藏地:
全部
電子資源
出版年:
卷號:
館藏
1 筆 • 頁數 1 •
1
條碼號
典藏地名稱
館藏流通類別
資料類型
索書號
使用類型
借閱狀態
預約狀態
備註欄
附件
W9073161
電子資源
11.線上閱覽_V
電子書
EB W9073161
一般使用(Normal)
在架
0
1 筆 • 頁數 1 •
1
多媒體
評論
新增評論
分享你的心得
Export
取書館
處理中
...
變更密碼
登入