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Interfacial charge transfer mechanis...

The Johns Hopkins University.

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Interfacial charge transfer mechanisms and cation effects in dye-sensitized solar cells.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Interfacial charge transfer mechanisms and cation effects in dye-sensitized solar cells./
Author:	Staniszewski, Aaron J.
Description:	141 p.
Notes:	Adviser: Gerald J. Meyer.
Contained By:	Dissertation Abstracts International69-12B.
Subject:	Chemistry, Inorganic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3339998
ISBN:	9780549939825

Interfacial charge transfer mechanisms and cation effects in dye-sensitized solar cells.
Staniszewski, Aaron J.

Interfacial charge transfer mechanisms and cation effects in dye-sensitized solar cells. - 141 p.

Adviser: Gerald J. Meyer.

Thesis (Ph.D.)--The Johns Hopkins University, 2009.

The contents herein this thesis report on mechanistic processes important for the dye-sensitized solar cell (DSSC) with a focus on the influential nature of small cations at the interface. Chapter 1 introduces the reader to the DSSC by describing the accepted mechanism of a functioning cell and detailing its working components. Chapter 2 reports on a novel strategy aimed to improve device efficiencies and exceed the Shockley-Queisser limit, a well-known theoretical solar-to-electrical energy conversion efficiency standard. This strategy uses the ultrafast electron injection properties of the TiO2 to produce products from sunlight that are uphill in fluid solution. In Chapter 3, the mechanism of recombination of this charge-separated state is studied using chronoabsorption measurements. It is proposed that while the hole transport is limited through self-exchange reactions, the conduction band states of TiO2 mediate electron transport. Potential determining cations were introduced to "tune" the electron diffusion rates. Chapter 4 reports on a high-extinction ruthenium compound for its use as a sensitizer. Interestingly, after photo-oxidation of this compound on TiO2, the hole transferred out to a remote ligand, increasing the charge separation distance. Cation motion was studied in Chapter 5 using a novel ruthenium(II) compound that underwent large spectroscopic changes when exposed to lithium cations. These absorption changes allowed the determination of its transport mechanism at the interface during electron injection and charge recombination.

ISBN: 9780549939825Subjects--Topical Terms:

517253
Chemistry, Inorganic.

Interfacial charge transfer mechanisms and cation effects in dye-sensitized solar cells.
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035 $a (UMI)AAI3339998
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100 1 $a Staniszewski, Aaron J. $3 1018489
245 1 0 $a Interfacial charge transfer mechanisms and cation effects in dye-sensitized solar cells.
300 $a 141 p.
500 $a Adviser: Gerald J. Meyer.
500 $a Source: Dissertation Abstracts International, Volume: 69-12, Section: B, page: 7506.
502 $a Thesis (Ph.D.)--The Johns Hopkins University, 2009.
520 $a The contents herein this thesis report on mechanistic processes important for the dye-sensitized solar cell (DSSC) with a focus on the influential nature of small cations at the interface. Chapter 1 introduces the reader to the DSSC by describing the accepted mechanism of a functioning cell and detailing its working components. Chapter 2 reports on a novel strategy aimed to improve device efficiencies and exceed the Shockley-Queisser limit, a well-known theoretical solar-to-electrical energy conversion efficiency standard. This strategy uses the ultrafast electron injection properties of the TiO2 to produce products from sunlight that are uphill in fluid solution. In Chapter 3, the mechanism of recombination of this charge-separated state is studied using chronoabsorption measurements. It is proposed that while the hole transport is limited through self-exchange reactions, the conduction band states of TiO2 mediate electron transport. Potential determining cations were introduced to "tune" the electron diffusion rates. Chapter 4 reports on a high-extinction ruthenium compound for its use as a sensitizer. Interestingly, after photo-oxidation of this compound on TiO2, the hole transferred out to a remote ligand, increasing the charge separation distance. Cation motion was studied in Chapter 5 using a novel ruthenium(II) compound that underwent large spectroscopic changes when exposed to lithium cations. These absorption changes allowed the determination of its transport mechanism at the interface during electron injection and charge recombination.
590 $a School code: 0098.
650 4 $a Chemistry, Inorganic. $3 517253
650 4 $a Chemistry, Physical. $3 560527
650 4 $a Energy. $3 876794
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710 2 $a The Johns Hopkins University. $3 1017431
773 0 $t Dissertation Abstracts International $g 69-12B.
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791 $a Ph.D.
792 $a 2009
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3339998