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Selective Organocatalytic Ring-Opening Polymerization of Cyclic Esters and Carbonates.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Selective Organocatalytic Ring-Opening Polymerization of Cyclic Esters and Carbonates./
作者:	Jadrich, Caleb Nathaniel.
面頁冊數:	1 online resource (258 pages)
附註:	Source: Dissertations Abstracts International, Volume: 84-12, Section: A.
Contained By:	Dissertations Abstracts International84-12A.
標題:	Ecology. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30462657click for full text (PQDT)
ISBN:	9798379653811

Selective Organocatalytic Ring-Opening Polymerization of Cyclic Esters and Carbonates.
Jadrich, Caleb Nathaniel.

Selective Organocatalytic Ring-Opening Polymerization of Cyclic Esters and Carbonates. - 1 online resource (258 pages)

Source: Dissertations Abstracts International, Volume: 84-12, Section: A.

Thesis (Ph.D.)--Stanford University, 2023.

Includes bibliographical references

Chapter 1 introduces polyesters as sustainable alternatives to traditional petroleumbased plastics, including biorenewable sourcing, degradability, and methods of synthesis and manufacture. It specifically highlights the advantages of polyesters produced by ringopening polymerization (ROP) and manufactured by additive manufacturing technologies.Chapter 2 describes a catalyst system comprising a hindered base and a primary alcohol initiator which can be utilized for controlled, ultrafast polymerization cyclic monomers when utilized in conjunction with a continuous flow reactor. It highlights the advantages of continuous flow reactors for improving reaction control.Chapter 3 describes a fast, selective organocatalyst for the ROP of cyclic esters and carbonates that functions by simultaneous activation through hydrogen bonding while the monomer is activated by the bound counter ion.Chapter 4 discusses recent developments in the synthesis of polyester resins by ROP, and the mechanical properties of parts generated from them using continuous liquid interface production (CLIP) additive manufacturing.Appendix 1, Appendix 2, and Appendix 3 serve as supplementary information about the materials, methods, and results from Chapter 2, Chapter 3, and Chapter 4, respectively.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2023

Mode of access: World Wide Web

ISBN: 9798379653811Subjects--Topical Terms:

516476
Ecology.
Index Terms--Genre/Form:

542853
Electronic books.

Selective Organocatalytic Ring-Opening Polymerization of Cyclic Esters and Carbonates.
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502 $a Thesis (Ph.D.)--Stanford University, 2023.
504 $a Includes bibliographical references
520 $a Chapter 1 introduces polyesters as sustainable alternatives to traditional petroleumbased plastics, including biorenewable sourcing, degradability, and methods of synthesis and manufacture. It specifically highlights the advantages of polyesters produced by ringopening polymerization (ROP) and manufactured by additive manufacturing technologies.Chapter 2 describes a catalyst system comprising a hindered base and a primary alcohol initiator which can be utilized for controlled, ultrafast polymerization cyclic monomers when utilized in conjunction with a continuous flow reactor. It highlights the advantages of continuous flow reactors for improving reaction control.Chapter 3 describes a fast, selective organocatalyst for the ROP of cyclic esters and carbonates that functions by simultaneous activation through hydrogen bonding while the monomer is activated by the bound counter ion.Chapter 4 discusses recent developments in the synthesis of polyester resins by ROP, and the mechanical properties of parts generated from them using continuous liquid interface production (CLIP) additive manufacturing.Appendix 1, Appendix 2, and Appendix 3 serve as supplementary information about the materials, methods, and results from Chapter 2, Chapter 3, and Chapter 4, respectively.
533 $a Electronic reproduction. $b Ann Arbor, Mich. : $c ProQuest, $d 2023
538 $a Mode of access: World Wide Web
650 4 $a Ecology. $3 516476
650 4 $a Polymers. $3 535398
650 4 $a Raw materials. $3 648907
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650 4 $a Resins. $3 3682318
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650 4 $a Cellulose. $3 588995
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650 4 $a Carbohydrates. $3 522687
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650 4 $a Copolymers. $3 1073457
650 4 $a Molecular weight. $3 3683783
650 4 $a Biomass. $3 1013462
650 4 $a Energy. $3 876794
650 4 $a Potassium. $3 3562093
650 4 $a Landfill. $3 3548474
650 4 $a Industrial engineering. $3 526216
650 4 $a Materials science. $3 543314
650 4 $a Plastics. $3 649803
650 4 $a Polymer chemistry. $3 3173488
650 4 $a Sustainability. $3 1029978
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