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Design, synthesis, and characterization of a tetraamide macrocyclic ligand and its iron- complex for green oxidation chemistry.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Design, synthesis, and characterization of a tetraamide macrocyclic ligand and its iron- complex for green oxidation chemistry./
作者:	Sullivan, Shane Z.
面頁冊數:	1 online resource (66 pages)
附註:	Source: Masters Abstracts International, Volume: 72-03.
Contained By:	Masters Abstracts International72-03.
標題:	Organic chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1479784click for full text (PQDT)
ISBN:	9781124156552

Design, synthesis, and characterization of a tetraamide macrocyclic ligand and its iron- complex for green oxidation chemistry.
Sullivan, Shane Z.

Design, synthesis, and characterization of a tetraamide macrocyclic ligand and its iron- complex for green oxidation chemistry. - 1 online resource (66 pages)

Source: Masters Abstracts International, Volume: 72-03.

Thesis (M.S.)--University of Arkansas at Little Rock, 2010.

Includes bibliographical references

This work presents the spectroscopic characterization and catalytic investigation of a FeIII-complex of a tetraamidomacrocyclic ligand. Under catalytic conditions the complex is soluble in aqueous solutions and rapidly activates hydrogen peroxide under mild reaction conditions. Both the kinetics and extent of water-soluble dye and paper effluent H2O 2-bleaching catalyzed was found to be comparable to known Fe III-TAML complexes. As an additional application, the complex showed potential for the synthesis of a variety of N-oxides from their corresponding amines as demonstrated by its high turnover number and essentially stoichiometric yield in selected amines. Electrospray ionization-mass spectrometry of the complex reveals a peak at 418 m/z and isotopic distribution which accurately matches the theoretically predicted mass spectrum. Cyclic voltammetry in acetonitrile shows a one-electron event at E1/2 = 0.50 V versus Ag/AgCl electrode. The magnetic moment (μeff = 3.87 BM) was measured by the Gouy method and correlated with EPR spectroscopy.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2023

Mode of access: World Wide Web

ISBN: 9781124156552Subjects--Topical Terms:

523952
Organic chemistry.
Subjects--Index Terms:

IronIndex Terms--Genre/Form:

542853
Electronic books.

Design, synthesis, and characterization of a tetraamide macrocyclic ligand and its iron- complex for green oxidation chemistry.
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500 $a Source: Masters Abstracts International, Volume: 72-03.
500 $a Publisher info.: Dissertation/Thesis.
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502 $a Thesis (M.S.)--University of Arkansas at Little Rock, 2010.
504 $a Includes bibliographical references
520 $a This work presents the spectroscopic characterization and catalytic investigation of a FeIII-complex of a tetraamidomacrocyclic ligand. Under catalytic conditions the complex is soluble in aqueous solutions and rapidly activates hydrogen peroxide under mild reaction conditions. Both the kinetics and extent of water-soluble dye and paper effluent H2O 2-bleaching catalyzed was found to be comparable to known Fe III-TAML complexes. As an additional application, the complex showed potential for the synthesis of a variety of N-oxides from their corresponding amines as demonstrated by its high turnover number and essentially stoichiometric yield in selected amines. Electrospray ionization-mass spectrometry of the complex reveals a peak at 418 m/z and isotopic distribution which accurately matches the theoretically predicted mass spectrum. Cyclic voltammetry in acetonitrile shows a one-electron event at E1/2 = 0.50 V versus Ag/AgCl electrode. The magnetic moment (μeff = 3.87 BM) was measured by the Gouy method and correlated with EPR spectroscopy.
533 $a Electronic reproduction. $b Ann Arbor, Mich. : $c ProQuest, $d 2023
538 $a Mode of access: World Wide Web
650 4 $a Organic chemistry. $3 523952
653 $a Iron
653 $a Oxidation
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