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Corrosion Propagation of Reinforcing Steel Embedded in Binary and Ternary Concrete.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Corrosion Propagation of Reinforcing Steel Embedded in Binary and Ternary Concrete./
作者:	Hoque, Kazi Naimul.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, : 2020,
面頁冊數:	231 p.
附註:	Source: Dissertations Abstracts International, Volume: 82-07, Section: B.
Contained By:	Dissertations Abstracts International82-07B.
標題:	Ocean engineering. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28264378
ISBN:	9798557058223

Corrosion Propagation of Reinforcing Steel Embedded in Binary and Ternary Concrete.
Hoque, Kazi Naimul.

Corrosion Propagation of Reinforcing Steel Embedded in Binary and Ternary Concrete. - Ann Arbor : ProQuest Dissertations & Theses, 2020 - 231 p.

Source: Dissertations Abstracts International, Volume: 82-07, Section: B.

Thesis (Ph.D.)--Florida Atlantic University, 2020.

This item must not be sold to any third party vendors.

The Florida Department of Transportation (FDOT) has been using supplementary cementitious materials while constructing steel reinforced concrete marine bridge structures for over three decades. It has been found from previous studies that such additions in concrete mix makes the concrete more durable. This research was conducted to better understand the corrosion propagation stage of steel rebar embedded in high performance concrete exposed to high humidity environment. Reinforced concrete samples that were made with binary mixes, and ternary mixes were considered. None of these concretes had any admixed chloride to start with. An accelerated chloride transport method was used to drive chloride ions into the concrete so that chlorides reached and exceed the chloride threshold at the rebar surface and hence the corrosion process initiated after a short period of time (within few days to few months). Once corrosion has initiated the corrosion propagation can be studied. Electrochemical measurements such as rebar potential measurements, Linear Polarization Resistance (LPR), Electrochemical Impedance Spectroscopy (EIS), and Galvanostatic Pulse (GP) measurements were taken at regular intervals (during and after the electro-migration process) to observe the corrosion propagation in each sample. During the propagation stage, reinforcement eventually reached negative potentials values (i.e., Ecorr≤ -0.200 Vsce) for all the samples. The corrected polarization resistance (Rc) was calculated by subtracting the concrete solution resistance from the apparent polarization resistance measured. The Rc values obtained from LPR and GP measurements were converted to corrosion current (as the corroding area is unknown), and these corrosion current values measured over time were used to obtain the calculated mass loss (using Faraday's Law). A comparison was made of the calculated corrosion current obtained using the LPR and GP tests. A comparison of mass loss was also obtained from the values measured from LPR and GP tests. From the experimental results, it was observed that the corrosion current values were largely dependent on the length of solution reservoirs. For specimens cast with single rebar as well as three rebars, the most recent corrosion current values (measurements taken between July 2018 to October 2020) in general were larger for the rebars that are embedded in specimens prepared with SL mix, followed by specimens prepared with FA, T1, and T2 mixes respectively. The range of corrosion current values (most recent) were 0.8-33.8 μA for SL samples, 0.5-22.5 μA for FA samples, 0.8-14.8 μA for T1 samples, and 0.7-10.4 μA for T2 samples respectively. It was also found that the calculated mass loss values were larger for rebars that are embedded in specimens (single rebar and three rebars) prepared with SL mix, followed by specimens prepared with FA, T1, and T2 mixes respectively. The range of calculated mass loss values were 0.07-1.13 grams for SL samples, 0.06-0.62 grams for FA samples, 0.12-0.54 grams for T1 samples, and 0.06-0.40 grams for T2 samples respectively. A variety of corrosion related parameters (Ecorr, Rs, Rc, and Icorr) and calculated theoretical mass loss values observed, were due to the changing parameters such as concrete compositions, concrete cover thickness, rebar diameter, total ampere-hour applied, and reservoir size. The specimens showed no visual signs of corrosion such as cracks or corrosion products that reached the concrete surface. The actual size of the corroding sites was unknown as the specimens were not terminated for forensic analysis. The size of the corroding sites could affect how much corrosion products are required to crack the concrete. It is speculated that the corrosion products in liquid form penetrated the pore structure but did not build up enough to cause cracks. No cracks or corrosion bleed outs were observed within the monitored propagation period of approximately 1600 days.

ISBN: 9798557058223Subjects--Topical Terms:

660731
Ocean engineering.
Subjects--Index Terms:

Binary and ternary concrete

Corrosion Propagation of Reinforcing Steel Embedded in Binary and Ternary Concrete.
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245 1 0 $a Corrosion Propagation of Reinforcing Steel Embedded in Binary and Ternary Concrete.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2020
300 $a 231 p.
500 $a Source: Dissertations Abstracts International, Volume: 82-07, Section: B.
500 $a Advisor: Presuel-Moreno, Francisco.
502 $a Thesis (Ph.D.)--Florida Atlantic University, 2020.
506 $a This item must not be sold to any third party vendors.
520 $a The Florida Department of Transportation (FDOT) has been using supplementary cementitious materials while constructing steel reinforced concrete marine bridge structures for over three decades. It has been found from previous studies that such additions in concrete mix makes the concrete more durable. This research was conducted to better understand the corrosion propagation stage of steel rebar embedded in high performance concrete exposed to high humidity environment. Reinforced concrete samples that were made with binary mixes, and ternary mixes were considered. None of these concretes had any admixed chloride to start with. An accelerated chloride transport method was used to drive chloride ions into the concrete so that chlorides reached and exceed the chloride threshold at the rebar surface and hence the corrosion process initiated after a short period of time (within few days to few months). Once corrosion has initiated the corrosion propagation can be studied. Electrochemical measurements such as rebar potential measurements, Linear Polarization Resistance (LPR), Electrochemical Impedance Spectroscopy (EIS), and Galvanostatic Pulse (GP) measurements were taken at regular intervals (during and after the electro-migration process) to observe the corrosion propagation in each sample. During the propagation stage, reinforcement eventually reached negative potentials values (i.e., Ecorr≤ -0.200 Vsce) for all the samples. The corrected polarization resistance (Rc) was calculated by subtracting the concrete solution resistance from the apparent polarization resistance measured. The Rc values obtained from LPR and GP measurements were converted to corrosion current (as the corroding area is unknown), and these corrosion current values measured over time were used to obtain the calculated mass loss (using Faraday's Law). A comparison was made of the calculated corrosion current obtained using the LPR and GP tests. A comparison of mass loss was also obtained from the values measured from LPR and GP tests. From the experimental results, it was observed that the corrosion current values were largely dependent on the length of solution reservoirs. For specimens cast with single rebar as well as three rebars, the most recent corrosion current values (measurements taken between July 2018 to October 2020) in general were larger for the rebars that are embedded in specimens prepared with SL mix, followed by specimens prepared with FA, T1, and T2 mixes respectively. The range of corrosion current values (most recent) were 0.8-33.8 μA for SL samples, 0.5-22.5 μA for FA samples, 0.8-14.8 μA for T1 samples, and 0.7-10.4 μA for T2 samples respectively. It was also found that the calculated mass loss values were larger for rebars that are embedded in specimens (single rebar and three rebars) prepared with SL mix, followed by specimens prepared with FA, T1, and T2 mixes respectively. The range of calculated mass loss values were 0.07-1.13 grams for SL samples, 0.06-0.62 grams for FA samples, 0.12-0.54 grams for T1 samples, and 0.06-0.40 grams for T2 samples respectively. A variety of corrosion related parameters (Ecorr, Rs, Rc, and Icorr) and calculated theoretical mass loss values observed, were due to the changing parameters such as concrete compositions, concrete cover thickness, rebar diameter, total ampere-hour applied, and reservoir size. The specimens showed no visual signs of corrosion such as cracks or corrosion products that reached the concrete surface. The actual size of the corroding sites was unknown as the specimens were not terminated for forensic analysis. The size of the corroding sites could affect how much corrosion products are required to crack the concrete. It is speculated that the corrosion products in liquid form penetrated the pore structure but did not build up enough to cause cracks. No cracks or corrosion bleed outs were observed within the monitored propagation period of approximately 1600 days.
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650 4 $a Civil engineering. $3 860360
650 4 $a Materials science. $3 543314
653 $a Binary and ternary concrete
653 $a Carbon steel
653 $a Corrosion current
653 $a Corrosion propagation
653 $a Galvanostatic pulse measurements
653 $a Mass loss
690 $a 0547
690 $a 0543
690 $a 0794
710 2 $a Florida Atlantic University. $b Ocean Engineering. $3 3173823
773 0 $t Dissertations Abstracts International $g 82-07B.
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791 $a Ph.D.
792 $a 2020
793 $a English
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