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Chalcogenide Perovskites for Solar E...

Perera, Samanthe.

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Chalcogenide Perovskites for Solar Energy Harvesting.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Chalcogenide Perovskites for Solar Energy Harvesting./
作者:	Perera, Samanthe.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, : 2017,
面頁冊數:	98 p.
附註:	Source: Dissertations Abstracts International, Volume: 78-09, Section: B.
Contained By:	Dissertations Abstracts International78-09B.
標題:	Nanoscience. -
電子資源:	https://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10255713
ISBN:	9781369593853

Chalcogenide Perovskites for Solar Energy Harvesting.
Perera, Samanthe.

Chalcogenide Perovskites for Solar Energy Harvesting. - Ann Arbor : ProQuest Dissertations & Theses, 2017 - 98 p.

Source: Dissertations Abstracts International, Volume: 78-09, Section: B.

Thesis (Ph.D.)--State University of New York at Buffalo, 2017.

This item must not be sold to any third party vendors.

Methylammonium Lead halide perovskites have recently emerged as a promising candidate for realizing high efficient low cost photovoltaic modules. Charge transport properties of the solution processed halide perovskites are comparable to some of the existing absorbers used in the current PV industry which require sophisticated processing techniques. Due to this simple processing required to achieve high efficiencies, halide perovskites have become an active field of research. As a result, perovskite solar cells are rapidly reaching towards theoretical efficiency limit of close to 30%. It's believed that ionicity inherent to perovskite materials is one of the contributing factors for the excellent charge transport properties of perovskites. Despite the growing interest for solar energy harvesting purposes, these halide perovskites have serious limitations such as toxicity and instability that need to be addressed in order to commercialize the solar cells incorporating them. This dissertation focuses on a new class of ionic semiconductors, chalcogenide perovskites for solar energy harvesting purposes. Coming from the family perovskites they are expected to have same excellent charge transport properties inherent to perovskites due to the ionicity. Inspired by few theoretical studies on chalcogenide perovskites, BaZrS3 and its Ti alloys were synthesized by sulfurizing the oxide counterpart. Structural characterizations have confirmed the predicted distorted perovskite phase. Optical characterizations have verified the direct band gap suitable for thin film single junction solar cells. Anion alloying was demonstrated by synthesizing oxysulfides with widely tunable band gap suitable for applications such as solid state lighting and sensing.

ISBN: 9781369593853Subjects--Topical Terms:

587832
Nanoscience.
Subjects--Index Terms:

Perovskite

Chalcogenide Perovskites for Solar Energy Harvesting.
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