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Redox Non-innocence and Formation of...

Pearce, Adam J.

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Redox Non-innocence and Formation of Nitrogen-Nitrogen Bonds in Organometallic Reactions.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Redox Non-innocence and Formation of Nitrogen-Nitrogen Bonds in Organometallic Reactions./
作者:	Pearce, Adam J.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, : 2020,
面頁冊數:	304 p.
附註:	Source: Dissertations Abstracts International, Volume: 81-10, Section: B.
Contained By:	Dissertations Abstracts International81-10B.
標題:	Inorganic chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=27735936
ISBN:	9781658425742

Redox Non-innocence and Formation of Nitrogen-Nitrogen Bonds in Organometallic Reactions.
Pearce, Adam J.

Redox Non-innocence and Formation of Nitrogen-Nitrogen Bonds in Organometallic Reactions. - Ann Arbor : ProQuest Dissertations & Theses, 2020 - 304 p.

Source: Dissertations Abstracts International, Volume: 81-10, Section: B.

Thesis (Ph.D.)--University of Minnesota, 2020.

This item must not be sold to any third party vendors.

The utilization of redox non-innocent ligands and substrates can grant access to new modes of reactivity in organometallic chemistry, allowing for the development of new sustainable methods with earth-abundant catalysts. Through the use of valence tautomerism in nitrogenous ligands and substrates (azides, azobenzene, isodiazenes, etc.), new organometallic reactions have been developed-the atom economical synthesis of important organic molecules such as pyrroles, pyrazoles and imines through titanium redox catalysis and an exploration of the valence tautomerism of an iridium(III)-hydrazido(2-) capable of oxidative addition.

ISBN: 9781658425742Subjects--Topical Terms:

3173556
Inorganic chemistry.
Subjects--Index Terms:

Catalysis

Redox Non-innocence and Formation of Nitrogen-Nitrogen Bonds in Organometallic Reactions.
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520 $a The utilization of redox non-innocent ligands and substrates can grant access to new modes of reactivity in organometallic chemistry, allowing for the development of new sustainable methods with earth-abundant catalysts. Through the use of valence tautomerism in nitrogenous ligands and substrates (azides, azobenzene, isodiazenes, etc.), new organometallic reactions have been developed-the atom economical synthesis of important organic molecules such as pyrroles, pyrazoles and imines through titanium redox catalysis and an exploration of the valence tautomerism of an iridium(III)-hydrazido(2-) capable of oxidative addition.
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