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Investigation of the foaming charact...
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Ramesh, Natarajan Subramanian.
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Investigation of the foaming characteristics of nucleation and growth of microcellular foams in polystyrene containing low glass transition particles.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Investigation of the foaming characteristics of nucleation and growth of microcellular foams in polystyrene containing low glass transition particles./
作者:
Ramesh, Natarajan Subramanian.
出版者:
Ann Arbor : ProQuest Dissertations & Theses, : 1993,
面頁冊數:
169 p.
附註:
Source: Dissertations Abstracts International, Volume: 54-12, Section: B.
Contained By:
Dissertations Abstracts International54-12B.
標題:
Chemical engineering. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=9311981
Investigation of the foaming characteristics of nucleation and growth of microcellular foams in polystyrene containing low glass transition particles.
Ramesh, Natarajan Subramanian.
Investigation of the foaming characteristics of nucleation and growth of microcellular foams in polystyrene containing low glass transition particles.
- Ann Arbor : ProQuest Dissertations & Theses, 1993 - 169 p.
Source: Dissertations Abstracts International, Volume: 54-12, Section: B.
Thesis (Ph.D.)--Clarkson University, 1993.
This item must not be sold to any third party vendors.
This work describes the evaluations of a new method to control nucleation and cell growth in microcellular polystyrene foams. It was determined that the nucleation in microcellular foam can be controlled by the addition of from 10$\\sp8$ to 10$\\sp $ rubber particles per cubic centimeter of unfoamed polymer. A new nucleation theory based on thermal activation of voids in the rubber particles has been developed. The prediction of this theory correlate with experimental data for the parameters of saturation pressure, foaming temperature, number of particles, particle size and particle size distribution. In addition to the investigation of nucleation, bubble growth was investigated from an experimental view point. Examination of the literature indicated that there were many models but little data. The results were compared with the Newtonian cell model originally proposed by Amon and Denson and a viscoelastic cell model later introduced by Arefmanesh and Advani. The predictions of the viscoelastic cell model were found to best fit the data. Data were obtained for both nitrogen and carbon dioxide as blowing agents and foaming was carried out at several saturation pressures and temperatures. In all cases the model seemed to correlate well with the experimental data.Subjects--Topical Terms:
560457
Chemical engineering.
Investigation of the foaming characteristics of nucleation and growth of microcellular foams in polystyrene containing low glass transition particles.
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This work describes the evaluations of a new method to control nucleation and cell growth in microcellular polystyrene foams. It was determined that the nucleation in microcellular foam can be controlled by the addition of from 10$\\sp8$ to 10$\\sp $ rubber particles per cubic centimeter of unfoamed polymer. A new nucleation theory based on thermal activation of voids in the rubber particles has been developed. The prediction of this theory correlate with experimental data for the parameters of saturation pressure, foaming temperature, number of particles, particle size and particle size distribution. In addition to the investigation of nucleation, bubble growth was investigated from an experimental view point. Examination of the literature indicated that there were many models but little data. The results were compared with the Newtonian cell model originally proposed by Amon and Denson and a viscoelastic cell model later introduced by Arefmanesh and Advani. The predictions of the viscoelastic cell model were found to best fit the data. Data were obtained for both nitrogen and carbon dioxide as blowing agents and foaming was carried out at several saturation pressures and temperatures. In all cases the model seemed to correlate well with the experimental data.
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