| 內容註: |
1. Introduction -- 2. General Kinetic Rules for Chemical Reactions, Collisional, and Intramolecular Processes -- 2.1. Rates of Reaction, Collisional, and Spontaneous Processes. Rate Constant. Kinetic Types of Simple Processes -- 2.2. Chemical Equilibrium. Equilibrium Constant -- 2.3. Arrhenius equation -- 2.4. Complex Reactions -- 2.4.1. Consecutive Reactions. Steady-state Method -- Problems -- References -- 3. Theory of Elementary Processes -- 3.1. Cross-sections, Rate Constants, and Probabilities of Elementary processes -- 3.2. The detailed balance principle. Adiabatic approximations. Potential Energy Curves and Surfaces -- 3.3. Descriptions of Collisional Processes using Potential Energy Curves and Surfaces. Intramolecular Vibrational Relaxation in Polyatomic Molecules -- 3.4. Non-adiabatic Transitions. Perturbation theory. Probabilities of Adiabatic and Non-adiabatic Transitions -- 3.5. Intermolecular Interactions. Types of Intermolecular Interactions -- 3.6. Semiempirical Model Potentials -- Problems -- References -- 4. Photoprocesses -- 4.1. Primary and Secondary Gas-Phase Photoprocesses. Quantum Yields of the Gas-Phase Photoprocesses -- 4.2. Optical Transitions. Selection Rules for Optical Transitions. Spin-Orbit Coupling and Spin-Forbidden Radiative Transitions -- 4.3. Absorption. Absorption Band Intensities. Einstein Transition Probabilities. Oscillator Strength. Transition Dipole Moment. Beer-Lambert Law -- 4.4. Franck-Condon Principle for Bound-bound and Bound-free Optical Transitions -- 4.5. Luminescence. Radiative lifetime. The Relationship between Einstein Transition Probabilities and Transition Dipole Moment -- 4.6. Intramolecular Perturbations. Selection Rules and Franck-Condon Principle for Intramolecular Perturbation. Perturbations between Bound States. Abnormally long Radiative Lifetime -- 4.7. Spontaneous Predissociation of Two-, Tri- and Polyatomic Molecules. Classes of Predissociation Processes -- 4.8. Photodecay of Two-, Tri- and Polyatomic Molecules. Long-lived States of Polyatomic Molecules -- References -- 5. Energy Transfer in Collisions -- 5.1. Translational-Translational Energy Transfer (T-T exchange) -- 5.2. Rotational-Translational Energy Transfer (R-T exchange) -- 5.3. Vibrational Energy Transfer (V-T, V-R,T Processes) -- 5.4. Non-adiabatic Coupling and Vibrational Energy Transfer -- 5.5. Collision-Induced Non-Adiabatic Transitions -- 5.6. Collision-Induced Predissociation -- 5.7. Vibrational Relaxation via Several Electronic States -- 5.8. Electronic Deactivation -- Problems -- References -- 6. Weakly-Bound Complexes -- 6.1. Hydrogen- and Halogen-Bond Complexes -- 6.2. Van der Waals Complexes. 6.3. Rare gas-halogen Molecule Clusters -- References -- 7. Termolecular reactions -- 7.1. Termolecular recombination. Mechanism of Termolecular Recombination -- References -- 8. Chemiluminescence -- 8.1. Classes of Chemiluminescence Processes.Gas-P Rate Constants -- 8.2. General Rules of Radiative Recombination -- References -- Solution of Problems -- Index. |