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Synthesis of optically active oxymet...
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Sawato, Tsukasa.
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Synthesis of optically active oxymethylenehelicene oligomers and self-assembly phenomena at a liquid-solid interface
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Synthesis of optically active oxymethylenehelicene oligomers and self-assembly phenomena at a liquid-solid interface/ by Tsukasa Sawato.
作者:
Sawato, Tsukasa.
出版者:
Singapore :Springer Singapore : : 2020.,
面頁冊數:
xii, 83 p. :ill. (some col.), digital ;24 cm.
內容註:
1. Introduction -- 2. Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid-Solid Interface -- 3. Mechanical Stirring Induces Heteroaggregate Formation and Self-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution -- 4. Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers -- 5. Conclusions -- 6. Experimental Section.
Contained By:
Springer eBooks
標題:
Oligomerization. -
電子資源:
https://doi.org/10.1007/978-981-15-3192-7
ISBN:
9789811531927
Synthesis of optically active oxymethylenehelicene oligomers and self-assembly phenomena at a liquid-solid interface
Sawato, Tsukasa.
Synthesis of optically active oxymethylenehelicene oligomers and self-assembly phenomena at a liquid-solid interface
[electronic resource] /by Tsukasa Sawato. - Singapore :Springer Singapore :2020. - xii, 83 p. :ill. (some col.), digital ;24 cm. - Springer theses,2190-5053. - Springer theses..
1. Introduction -- 2. Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid-Solid Interface -- 3. Mechanical Stirring Induces Heteroaggregate Formation and Self-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution -- 4. Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers -- 5. Conclusions -- 6. Experimental Section.
In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid-solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid-solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid-solid interfaces not found in solutions. Detailed results are provided for new chemical reactions at liquid-solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid-solid interface.
ISBN: 9789811531927
Standard No.: 10.1007/978-981-15-3192-7doiSubjects--Topical Terms:
3448084
Oligomerization.
LC Class. No.: QD382.O43 / S293 2020
Dewey Class. No.: 541.39
Synthesis of optically active oxymethylenehelicene oligomers and self-assembly phenomena at a liquid-solid interface
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1. Introduction -- 2. Fibril Film Formation of Pseudoenantiomeric Oxymethylenehelicene Oligomers at the Liquid-Solid Interface -- 3. Mechanical Stirring Induces Heteroaggregate Formation and Self-assembly of Pseudoenantiomeric Oxymethylenehelicene Oligomers in Solution -- 4. Proximate Stochastic Chiral Symmetry Breaking by Racemic Oxymethylenehelicene Oligomers -- 5. Conclusions -- 6. Experimental Section.
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In this book, the author demonstrates that double-helix formation and fibril film formation occur on solid surfaces as a result of the catalytic effect of the liquid-solid interface of the newly synthesized helicene oligomer. In addition, he shows that the double helix produced at the liquid-solid interface can be diffused into a solution to form a self-assembling material by means of mechanical stirring. Both types of formation are new chemical phenomena unique to liquid-solid interfaces not found in solutions. Detailed results are provided for new chemical reactions at liquid-solid interfaces, and gleaned from experiments performed using synthetic organic molecules. The book offers a useful reference guide to elucidating reaction mechanisms for researchers whose work involves chemical phenomena at a liquid-solid interface.
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