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Cycloaddition Reactions of Silyloxy ...

Haynes, Jamie-Ann Elaine.

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Cycloaddition Reactions of Silyloxy Vinylketene Iron Carbonyl Complexes with Alkynes.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Cycloaddition Reactions of Silyloxy Vinylketene Iron Carbonyl Complexes with Alkynes./
Author:	Haynes, Jamie-Ann Elaine.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2018,
Description:	97 p.
Notes:	Source: Masters Abstracts International, Volume: 57-06.
Contained By:	Masters Abstracts International57-06(E).
Subject:	Chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10868692
ISBN:	9780438079038

Cycloaddition Reactions of Silyloxy Vinylketene Iron Carbonyl Complexes with Alkynes.
Haynes, Jamie-Ann Elaine.

Cycloaddition Reactions of Silyloxy Vinylketene Iron Carbonyl Complexes with Alkynes. - Ann Arbor : ProQuest Dissertations & Theses, 2018 - 97 p.

Source: Masters Abstracts International, Volume: 57-06.

Thesis (M.S.)--Long Island University, The Brooklyn Center, 2018.

The focus of the series of experiments centers around [4+2] cycloaddition reactions between tricarbonyl iron(0) vinylketene complexes and alkynes. The procedure includes confirmation of a viable technique which allows for affordability without diminished productivity or effectiveness, with the substitution of iron, as it meets these requirements. The compounds selected included tricarbonyl [2-triisoproylsilyloxy (TIP SO) vinylketene] iron, tricarbonyl [2-TIPSO-3-methyl vinylketene] iron, tricarbonyl [2-TIPS0-4-methyl vinylketene] iron, tricarbonyl [2-TIPSO-3-phenyl vinylketene] iron, and tricarbonyl [2ethoxy-3phenyl vinylketene] iron; the alkynes vary between chlorohexyne and methyl propiolate (which was also analyzed as it reacted with tricarbonyl [2-TIPSO-3-methyl vinylketene] iron). These compounds were authenticated and used in the purest forms that could be provided, within the cyclization process, and cycloadducts then purified and identified through spectroscopic analysis. The success of high yields from the cycloadditions could provide cost effective means for synthesizing medications.

ISBN: 9780438079038Subjects--Topical Terms:

516420
Chemistry.

Cycloaddition Reactions of Silyloxy Vinylketene Iron Carbonyl Complexes with Alkynes.
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245 1 0 $a Cycloaddition Reactions of Silyloxy Vinylketene Iron Carbonyl Complexes with Alkynes.
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300 $a 97 p.
500 $a Source: Masters Abstracts International, Volume: 57-06.
500 $a Adviser: Samuel Watson.
502 $a Thesis (M.S.)--Long Island University, The Brooklyn Center, 2018.
520 $a The focus of the series of experiments centers around [4+2] cycloaddition reactions between tricarbonyl iron(0) vinylketene complexes and alkynes. The procedure includes confirmation of a viable technique which allows for affordability without diminished productivity or effectiveness, with the substitution of iron, as it meets these requirements. The compounds selected included tricarbonyl [2-triisoproylsilyloxy (TIP SO) vinylketene] iron, tricarbonyl [2-TIPSO-3-methyl vinylketene] iron, tricarbonyl [2-TIPS0-4-methyl vinylketene] iron, tricarbonyl [2-TIPSO-3-phenyl vinylketene] iron, and tricarbonyl [2ethoxy-3phenyl vinylketene] iron; the alkynes vary between chlorohexyne and methyl propiolate (which was also analyzed as it reacted with tricarbonyl [2-TIPSO-3-methyl vinylketene] iron). These compounds were authenticated and used in the purest forms that could be provided, within the cyclization process, and cycloadducts then purified and identified through spectroscopic analysis. The success of high yields from the cycloadditions could provide cost effective means for synthesizing medications.
590 $a School code: 0198.
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