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Metal-Catalyzed Stereoselective Alke...

Logan, Kaitlyn Marie.

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Metal-Catalyzed Stereoselective Alkene Carboboration.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Metal-Catalyzed Stereoselective Alkene Carboboration./
作者:	Logan, Kaitlyn Marie.
出版者:	Ann Arbor : ProQuest Dissertations & Theses, : 2018,
面頁冊數:	410 p.
附註:	Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
Contained By:	Dissertation Abstracts International79-09B(E).
標題:	Organic chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10812075
ISBN:	9780355922684

Metal-Catalyzed Stereoselective Alkene Carboboration.
Logan, Kaitlyn Marie.

Metal-Catalyzed Stereoselective Alkene Carboboration. - Ann Arbor : ProQuest Dissertations & Theses, 2018 - 410 p.

Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.

Thesis (Ph.D.)--Indiana University, 2018.

The development of methods to access molecules of increased complexity and synthetic utility from readily available chemical feedstocks is a central goal of synthetic organic chemistry. Towards this goal, we have developed new complementary strategies for the stereoselective carboboration of alkenes. In one approach, copper/palladium synergistic catalysis is utilized in the arylboration of activated alkenes. This paradigm serves as a platform to develop new strategies for stereospecific cross coupling and ultimately allows for the development of diastereoselective and enantioselective methods. Our efforts to extend this reactivity to unactivated alkenes led to the discovery of a nickel-catalyzed arylboration reaction. This discovery allows for diverse difunctionalization of a range of alkene substrates. This reaction represents a new manifold of reactivity in nickel catalysis.

ISBN: 9780355922684Subjects--Topical Terms:

523952
Organic chemistry.

Metal-Catalyzed Stereoselective Alkene Carboboration.
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