東華大學圖書館 |

Language: English

Help

回圖書館首頁

手機版館藏查詢

Back

Switch To: Labeled | MARC Mode | ISBD

Metal-Catalyzed Stereoselective Alke...

Logan, Kaitlyn Marie.

Linked to FindBook

Google Book

Amazon

博客來

Metal-Catalyzed Stereoselective Alkene Carboboration.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Metal-Catalyzed Stereoselective Alkene Carboboration./
Author:	Logan, Kaitlyn Marie.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2018,
Description:	410 p.
Notes:	Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
Contained By:	Dissertation Abstracts International79-09B(E).
Subject:	Organic chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10812075
ISBN:	9780355922684

Metal-Catalyzed Stereoselective Alkene Carboboration.
Logan, Kaitlyn Marie.

Metal-Catalyzed Stereoselective Alkene Carboboration. - Ann Arbor : ProQuest Dissertations & Theses, 2018 - 410 p.

Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.

Thesis (Ph.D.)--Indiana University, 2018.

The development of methods to access molecules of increased complexity and synthetic utility from readily available chemical feedstocks is a central goal of synthetic organic chemistry. Towards this goal, we have developed new complementary strategies for the stereoselective carboboration of alkenes. In one approach, copper/palladium synergistic catalysis is utilized in the arylboration of activated alkenes. This paradigm serves as a platform to develop new strategies for stereospecific cross coupling and ultimately allows for the development of diastereoselective and enantioselective methods. Our efforts to extend this reactivity to unactivated alkenes led to the discovery of a nickel-catalyzed arylboration reaction. This discovery allows for diverse difunctionalization of a range of alkene substrates. This reaction represents a new manifold of reactivity in nickel catalysis.

ISBN: 9780355922684Subjects--Topical Terms:

523952
Organic chemistry.

Metal-Catalyzed Stereoselective Alkene Carboboration.
LDR:01785nmm a2200289 4500 001 2202712
005 20190513114838.5
008 201008s2018 ||||||||||||||||| ||eng d
020 $a 9780355922684
035 $a (MiAaPQ)AAI10812075
035 $a (MiAaPQ)indiana:15209
035 $a AAI10812075
040 $a MiAaPQ $c MiAaPQ
100 1 $a Logan, Kaitlyn Marie. $3 3429483
245 1 0 $a Metal-Catalyzed Stereoselective Alkene Carboboration.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2018
300 $a 410 p.
500 $a Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
500 $a Adviser: Kevin Brown.
502 $a Thesis (Ph.D.)--Indiana University, 2018.
520 $a The development of methods to access molecules of increased complexity and synthetic utility from readily available chemical feedstocks is a central goal of synthetic organic chemistry. Towards this goal, we have developed new complementary strategies for the stereoselective carboboration of alkenes. In one approach, copper/palladium synergistic catalysis is utilized in the arylboration of activated alkenes. This paradigm serves as a platform to develop new strategies for stereospecific cross coupling and ultimately allows for the development of diastereoselective and enantioselective methods. Our efforts to extend this reactivity to unactivated alkenes led to the discovery of a nickel-catalyzed arylboration reaction. This discovery allows for diverse difunctionalization of a range of alkene substrates. This reaction represents a new manifold of reactivity in nickel catalysis.
590 $a School code: 0093.
650 4 $a Organic chemistry. $3 523952
690 $a 0490
710 2 $a Indiana University. $b Chemistry. $3 1020748
773 0 $t Dissertation Abstracts International $g 79-09B(E).
790 $a 0093
791 $a Ph.D.
792 $a 2018
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10812075