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Catalytic Asymmetric Desymmetrisatio...

Yi, Yi.

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Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization./
Author:	Yi, Yi.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2018,
Description:	318 p.
Notes:	Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
Contained By:	Dissertation Abstracts International79-09B(E).
Subject:	Organic chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10786363
ISBN:	9780355890662

Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.
Yi, Yi.

Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization. - Ann Arbor : ProQuest Dissertations & Theses, 2018 - 318 p.

Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.

Thesis (Ph.D.)--Michigan State University, 2018.

My doctorate research work with professor Borhan is mainly focused on developing new asymmetric halofunctionalization reactions. Chapter 1 describes the catalytic asymmetric desymmetrisation of dienes via chlorocyclization. Chapter 2 describes the kinetic resolution of propargyl amides via chlorocyclization. Both desymmetrisation and kinetic resolution using cinchona alkaloid (DHQD) 2PHAL as catalyst afford good diastereoselectivity and enantioselectivity. Chapter 3 discloses efforts to develop asymmetric ipso-halocyclization via dearomatization of phenol derivatives. Chapter 4 describes a novel and practical method to access N,O-acetals using commercially available XtalFluor-ERTM as catalyst.

ISBN: 9780355890662Subjects--Topical Terms:

523952
Organic chemistry.

Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.
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245 1 0 $a Catalytic Asymmetric Desymmetrisation and Kinetic Resolution of Unsaturated Amides via Halofunctionalization.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2018
300 $a 318 p.
500 $a Source: Dissertation Abstracts International, Volume: 79-09(E), Section: B.
500 $a Adviser: Babak Borhan.
502 $a Thesis (Ph.D.)--Michigan State University, 2018.
520 $a My doctorate research work with professor Borhan is mainly focused on developing new asymmetric halofunctionalization reactions. Chapter 1 describes the catalytic asymmetric desymmetrisation of dienes via chlorocyclization. Chapter 2 describes the kinetic resolution of propargyl amides via chlorocyclization. Both desymmetrisation and kinetic resolution using cinchona alkaloid (DHQD) 2PHAL as catalyst afford good diastereoselectivity and enantioselectivity. Chapter 3 discloses efforts to develop asymmetric ipso-halocyclization via dearomatization of phenol derivatives. Chapter 4 describes a novel and practical method to access N,O-acetals using commercially available XtalFluor-ERTM as catalyst.
590 $a School code: 0128.
650 4 $a Organic chemistry. $3 523952
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710 2 $a Michigan State University. $b Chemistry - Doctor of Philosophy. $3 2094041
773 0 $t Dissertation Abstracts International $g 79-09B(E).
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792 $a 2018
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856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10786363