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The significance of aryl-ether cleav...
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Ko, Chun-Han.
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The significance of aryl-ether cleavages in the alkaline delignification process.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
The significance of aryl-ether cleavages in the alkaline delignification process./
作者:
Ko, Chun-Han.
出版者:
Ann Arbor : ProQuest Dissertations & Theses, : 1993,
面頁冊數:
154 p.
附註:
Source: Masters Abstracts International, Volume: 32-05, page: 1327.
Contained By:
Masters Abstracts International32-05.
標題:
Wood sciences. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1356677
The significance of aryl-ether cleavages in the alkaline delignification process.
Ko, Chun-Han.
The significance of aryl-ether cleavages in the alkaline delignification process.
- Ann Arbor : ProQuest Dissertations & Theses, 1993 - 154 p.
Source: Masters Abstracts International, Volume: 32-05, page: 1327.
Thesis (M.S.)--State University of New York College of Environmental Science and Forestry, 1993.
This study evaluates the significance of aryl ether cleavages in the alkaline delignification of Norway spruce and aspen for both kraft and soda processes. The aryl ether-cleavage reaction was monitored by phenolic hydroxyl group generation in the pulp residual lignin as estimated by periodate oxidation method.Subjects--Topical Terms:
3168288
Wood sciences.
The significance of aryl-ether cleavages in the alkaline delignification process.
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Source: Masters Abstracts International, Volume: 32-05, page: 1327.
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This study evaluates the significance of aryl ether cleavages in the alkaline delignification of Norway spruce and aspen for both kraft and soda processes. The aryl ether-cleavage reaction was monitored by phenolic hydroxyl group generation in the pulp residual lignin as estimated by periodate oxidation method.
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In soda cooking, the extent of delignification up to about 90% level was closely related to aryl-ether hydrolysis reactions. Further delignification was relatively unaffected by the ether cleavage reaction. A similar trend was observed for aspen except displaying a distinct initial phase up to about 30% delignification. This initial delignification seems to be associated with the hydrolysis of few aryl ether units.
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The impact of aryl ether hydrolysis on alkaline delignification is equally comparable for both soda and kraft cooks and this was not considerably affected by pulping temperatures (160-180$\sp\circ$C), sulfidity, alkali concentration (0.5-1.5M) and AQ addition.
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Interestingly, a nearly linear "isokinetic" (enthalphy-entrophyl) relationship was observed for both the aryl ether-hydrolysis and delignification reactions. The kinetic data further support the significance of aryl-ather cleavages in the alkaline delignification process.
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