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Synthesis and functionalization of a...
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Liang, Yichen.
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Synthesis and functionalization of a triaryldiamine-base photoconductive/photorefractive composite, and its application to aberrated image restoration.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Synthesis and functionalization of a triaryldiamine-base photoconductive/photorefractive composite, and its application to aberrated image restoration./
作者:
Liang, Yichen.
出版者:
Ann Arbor : ProQuest Dissertations & Theses, : 2016,
面頁冊數:
114 p.
附註:
Source: Dissertation Abstracts International, Volume: 77-11(E), Section: B.
Contained By:
Dissertation Abstracts International77-11B(E).
標題:
Materials science. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10133094
ISBN:
9781339915869
Synthesis and functionalization of a triaryldiamine-base photoconductive/photorefractive composite, and its application to aberrated image restoration.
Liang, Yichen.
Synthesis and functionalization of a triaryldiamine-base photoconductive/photorefractive composite, and its application to aberrated image restoration.
- Ann Arbor : ProQuest Dissertations & Theses, 2016 - 114 p.
Source: Dissertation Abstracts International, Volume: 77-11(E), Section: B.
Thesis (Ph.D.)--Missouri University of Science and Technology, 2016.
Organic phoorefractive (PR) composites have recently emerged as an important class of materials for applications including high-density data storage, optical communication, and biomedical imaging. In an effort to further improve their performance, this study focused on the utilization of functionalized semiconductor nanocrystals to photosensitize triaryamine (TPD)-based PR composites, as well as the application of TPD-based PR composites in the restoration of aberrated optical information. A novel approach to functionalize CdSe quantum dot (QCdSe) was firstly introduced where the sulfonated triarydiamine (STPD) was used as charge-transporting ligand to passivate QCdSe. TPD-based photoconductive and PR composites were photosensitized with the STPD-passivated QCdSe (SQCdSe). Due to the charge-transporting capability of STPD, the composites photosensitized with STPD-capped QCdSe exhibited superior performance relative to composites employing more traditional photosensitizers (such as fullerene C60 and trioctylphosphine-capped QCdSe), with figures-of-merit including photoconductivities in excess of 60 pS/cm, two-beam coupling gain coefficients in excess of 110 cm-1, and PR response time of less than 30 ms. In addition, the ability of TPD-based PR composites to correct aberrations associated with a laser beam was described. Here, a severely aberrated laser beam was able to be restored to a nearly unaberrated condition through the PR process, and the potential of this technique for practical applications was well explained. Based on the current experimental geometry, a PR response time of 0.5 s was observed, which is the fastest PR response time reported for a PR composite operating under experimental conditions designed for the correction of optical aberrations.
ISBN: 9781339915869Subjects--Topical Terms:
543314
Materials science.
Synthesis and functionalization of a triaryldiamine-base photoconductive/photorefractive composite, and its application to aberrated image restoration.
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Organic phoorefractive (PR) composites have recently emerged as an important class of materials for applications including high-density data storage, optical communication, and biomedical imaging. In an effort to further improve their performance, this study focused on the utilization of functionalized semiconductor nanocrystals to photosensitize triaryamine (TPD)-based PR composites, as well as the application of TPD-based PR composites in the restoration of aberrated optical information. A novel approach to functionalize CdSe quantum dot (QCdSe) was firstly introduced where the sulfonated triarydiamine (STPD) was used as charge-transporting ligand to passivate QCdSe. TPD-based photoconductive and PR composites were photosensitized with the STPD-passivated QCdSe (SQCdSe). Due to the charge-transporting capability of STPD, the composites photosensitized with STPD-capped QCdSe exhibited superior performance relative to composites employing more traditional photosensitizers (such as fullerene C60 and trioctylphosphine-capped QCdSe), with figures-of-merit including photoconductivities in excess of 60 pS/cm, two-beam coupling gain coefficients in excess of 110 cm-1, and PR response time of less than 30 ms. In addition, the ability of TPD-based PR composites to correct aberrations associated with a laser beam was described. Here, a severely aberrated laser beam was able to be restored to a nearly unaberrated condition through the PR process, and the potential of this technique for practical applications was well explained. Based on the current experimental geometry, a PR response time of 0.5 s was observed, which is the fastest PR response time reported for a PR composite operating under experimental conditions designed for the correction of optical aberrations.
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