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Self-Assembled Monolayers at the Sol...

Frederick, Esther T.

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Self-Assembled Monolayers at the Solid-Liquid Interface: Design, Post-Modification and Effects of Molecular Variations as Compared to Homogenous Systems.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Self-Assembled Monolayers at the Solid-Liquid Interface: Design, Post-Modification and Effects of Molecular Variations as Compared to Homogenous Systems./
Author:	Frederick, Esther T.
Published:	Ann Arbor : ProQuest Dissertations & Theses, : 2016,
Description:	148 p.
Notes:	Source: Dissertation Abstracts International, Volume: 77-11(E), Section: B.
Contained By:	Dissertation Abstracts International77-11B(E).
Subject:	Physical chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10120422
ISBN:	9781339816043

Self-Assembled Monolayers at the Solid-Liquid Interface: Design, Post-Modification and Effects of Molecular Variations as Compared to Homogenous Systems.
Frederick, Esther T.

Self-Assembled Monolayers at the Solid-Liquid Interface: Design, Post-Modification and Effects of Molecular Variations as Compared to Homogenous Systems. - Ann Arbor : ProQuest Dissertations & Theses, 2016 - 148 p.

Source: Dissertation Abstracts International, Volume: 77-11(E), Section: B.

Thesis (Ph.D.)--Princeton University, 2016.

This item is not available from ProQuest Dissertations & Theses.

Since the dawn of chemistry, the study of reactions has taken place in homogenous systems. There is a wealth of knowledge relating to the kinetics and thermodynamics of such reactions. However, the increasingly smaller materials used in today's advancing technology requires novel heterogeneous chemistries at solid-liquid interfaces. Control over surface chemistry has numerous applications, including increasing biocompatibility for medical use, catalysis, improving cosmetic products and developing novel electronic devices. As we move toward a world with self-healing materials, single molecule circuits and nanoscale machines, the ability to attach molecules to a surface in a well-organized fashion is increasingly important.

ISBN: 9781339816043Subjects--Topical Terms:

1981412
Physical chemistry.

Self-Assembled Monolayers at the Solid-Liquid Interface: Design, Post-Modification and Effects of Molecular Variations as Compared to Homogenous Systems.
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100 1 $a Frederick, Esther T. $3 3282387
245 1 0 $a Self-Assembled Monolayers at the Solid-Liquid Interface: Design, Post-Modification and Effects of Molecular Variations as Compared to Homogenous Systems.
260 1 $a Ann Arbor : $b ProQuest Dissertations & Theses, $c 2016
300 $a 148 p.
500 $a Source: Dissertation Abstracts International, Volume: 77-11(E), Section: B.
500 $a Adviser: Steven L. Bernasek.
502 $a Thesis (Ph.D.)--Princeton University, 2016.
506 $a This item is not available from ProQuest Dissertations & Theses.
520 $a Since the dawn of chemistry, the study of reactions has taken place in homogenous systems. There is a wealth of knowledge relating to the kinetics and thermodynamics of such reactions. However, the increasingly smaller materials used in today's advancing technology requires novel heterogeneous chemistries at solid-liquid interfaces. Control over surface chemistry has numerous applications, including increasing biocompatibility for medical use, catalysis, improving cosmetic products and developing novel electronic devices. As we move toward a world with self-healing materials, single molecule circuits and nanoscale machines, the ability to attach molecules to a surface in a well-organized fashion is increasingly important.
520 $a Astoundingly, under appropriate conditions, single molecules self-arrange into highly ordered nanomaterials using guidelines internally coded by its elements and their arrangement in the molecule. Being able to exploit self-assembly is invaluable to successful fast-paced engineering of nanomaterials. However, quantifying the interplay between forces and developing a predictive model for 2D self-assembly is to date unsolved. An additional question that largely remains unanswered is, to what extent can relationships known from homogenous chemistry aid in understanding the self-assembly of heterogeneous systems? The work in thesis was motivated by these fundamental problems.
520 $a This thesis includes studies of both physisorbed and chemisorbed systems. Chapters 3 and 4 explore the effect of H-bonding and van der Waals interactions on physisorbed self-assembled monolayer (SAM) morphology using a series of 5-alkoxyisophthalamides and 5-alkoxyisophthalic acids on HOPG. The relationship between self-assembly in heterogeneous versus homogenous phases was examined in Chapter 3 and continued in chemisorbed systems in Chapter 5. The results of substituent effects on formation kinetic studies of chemisorbed styrene SAMs on H-Si fit to equations quantifying substituent effects in homogenous reactions. These studies provide evidence for the success in applying well quantified homogeneous relationships to lesser explored chemistry at a solid-liquid interface.
520 $a As interest in unique surface functionalization grew, this thesis expanded to include collaborations requiring surfaces exhibiting specific properties. These projects, described in Chapter 6 and 7, include surface assemblies for fullerene bombardment and SAMs for quantum control experiments. The design, post-modification and characterization of Si-phosphonate and Au-carbene linked SAMs for designated applications are presented.
590 $a School code: 0181.
650 4 $a Physical chemistry. $3 1981412
650 4 $a Materials science. $3 543314
650 4 $a Nanoscience. $3 587832
650 4 $a Molecular chemistry. $3 1071612
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710 2 $a Princeton University. $b Chemistry. $3 2094742
773 0 $t Dissertation Abstracts International $g 77-11B(E).
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793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10120422