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Gas-Phase Ion Chemistry: Kinetics an...
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Nichols, Charles M.
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Gas-Phase Ion Chemistry: Kinetics and Thermodynamics.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Gas-Phase Ion Chemistry: Kinetics and Thermodynamics./
作者:
Nichols, Charles M.
出版者:
Ann Arbor : ProQuest Dissertations & Theses, : 2016,
面頁冊數:
162 p.
附註:
Source: Dissertation Abstracts International, Volume: 77-10(E), Section: B.
Contained By:
Dissertation Abstracts International77-10B(E).
標題:
Physical chemistry. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10108688
ISBN:
9781339720241
Gas-Phase Ion Chemistry: Kinetics and Thermodynamics.
Nichols, Charles M.
Gas-Phase Ion Chemistry: Kinetics and Thermodynamics.
- Ann Arbor : ProQuest Dissertations & Theses, 2016 - 162 p.
Source: Dissertation Abstracts International, Volume: 77-10(E), Section: B.
Thesis (Ph.D.)--University of Colorado at Boulder, 2016.
This thesis employs gas-phase ion chemistry to study the kinetics and thermodynamics of chemical reactions and molecular properties. Gas-phase ion chemistry is important in diverse regions of the universe. It is directly relevant to the chemistry occurring in the atmospheres of planets and moons as well as the molecular clouds of the interstellar medium. Gas-phase ion chemistry is also employed to determine fundamental properties, such as the proton and electron affinities of molecules. Furthermore, gas-phase ion chemistry can be used to study chemical events that typically occur in the condensed-phase, such as prototypical organic reactions, in an effort to reveal the intrinsic properties and mechanisms of chemical reactions.
ISBN: 9781339720241Subjects--Topical Terms:
1981412
Physical chemistry.
Gas-Phase Ion Chemistry: Kinetics and Thermodynamics.
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Advisers: Veronica M. Bierbaum; William C. Lineberger.
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Mass spectrometry is used to investigate the reactivity and fundamental properties of ions. Kinetic data for reactions between cations or anions with neutral atoms or molecules is acquired using the selected ion flow tube (SIFT). These data are interpreted mechanistically and thermodynamically using literature data and theoretical computations. Additionally, the proton affinities of a series of anions are determined using a triple quadrupole mass spectrometer by investigating the collision induced dissociation of proton-bound, anionic heterodimers.
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The SIFT is coupled with a variety of ion-generation techniques. This thesis reports the design and operation of a new electrospray ion source for the SIFT in detail. The electrospray ionization technique allows ions that are pre-formed in the condensed-phase to be transmitted into the gas-phase for studies of their reactivity.
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