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Metal-catalyzed asymmetric epoxidati...

Luo, Lan.

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Metal-catalyzed asymmetric epoxidation and its related reactions.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Metal-catalyzed asymmetric epoxidation and its related reactions./
Author:	Luo, Lan.
Description:	309 p.
Notes:	Source: Dissertation Abstracts International, Volume: 77-10(E), Section: B.
Contained By:	Dissertation Abstracts International77-10B(E).
Subject:	Organic chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10129544
ISBN:	9781339874357

Metal-catalyzed asymmetric epoxidation and its related reactions.
Luo, Lan.

Metal-catalyzed asymmetric epoxidation and its related reactions. - 309 p.

Source: Dissertation Abstracts International, Volume: 77-10(E), Section: B.

Thesis (Ph.D.)--The University of Chicago, 2016.

Many important problems remain to be solved in catalytic asymmetric epoxidation, despite substantial progress in the past three decades. We drew our inspirations from the reactivity of metalloenzymes such as cytochrome P-450 and vanadium haloperoxidase, which perform some of the most difficult chemical transformations. Through carefully designed ancillary ligands, we have achieved asymmetric epoxidation and related functionalizations on a broad scope of substrates to afford products that were previously difficult to access.

ISBN: 9781339874357Subjects--Topical Terms:

523952
Organic chemistry.

Metal-catalyzed asymmetric epoxidation and its related reactions.
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100 1 $a Luo, Lan. $3 1905906
245 1 0 $a Metal-catalyzed asymmetric epoxidation and its related reactions.
300 $a 309 p.
500 $a Source: Dissertation Abstracts International, Volume: 77-10(E), Section: B.
500 $a Adviser: Hisashi Yamamoto.
502 $a Thesis (Ph.D.)--The University of Chicago, 2016.
520 $a Many important problems remain to be solved in catalytic asymmetric epoxidation, despite substantial progress in the past three decades. We drew our inspirations from the reactivity of metalloenzymes such as cytochrome P-450 and vanadium haloperoxidase, which perform some of the most difficult chemical transformations. Through carefully designed ancillary ligands, we have achieved asymmetric epoxidation and related functionalizations on a broad scope of substrates to afford products that were previously difficult to access.
520 $a This dissertation will include 1) iron-phenanthroline catalyzed asymmetric epoxidation of alpha, beta-unsaturated esters; 2) tandem enantioselective epoxidation and ring-opening kinetic resolution for the synthesis of virtually enantiopure aminodiols; and 3) synthetic studies towards (+)-catharanthine.
590 $a School code: 0330.
650 4 $a Organic chemistry. $3 523952
690 $a 0490
710 2 $a The University of Chicago. $b Chemistry. $3 1675066
773 0 $t Dissertation Abstracts International $g 77-10B(E).
790 $a 0330
791 $a Ph.D.
792 $a 2016
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=10129544