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Synthesis and characterization of or...

Mahammad, Saleempasha.

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Synthesis and characterization of organic linkers functionalized by crown ethers for metal-organic frameworks.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Synthesis and characterization of organic linkers functionalized by crown ethers for metal-organic frameworks./
作者:	Mahammad, Saleempasha.
面頁冊數:	122 p.
附註:	Source: Masters Abstracts International, Volume: 51-02.
Contained By:	Masters Abstracts International51-02(E).
標題:	Organic chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1518749
ISBN:	9781267620064

Synthesis and characterization of organic linkers functionalized by crown ethers for metal-organic frameworks.
Mahammad, Saleempasha.

Synthesis and characterization of organic linkers functionalized by crown ethers for metal-organic frameworks. - 122 p.

Source: Masters Abstracts International, Volume: 51-02.

Thesis (M.S.)--Lamar University - Beaumont, 2012.

Metal-organic frameworks (MOFs) recently emerged as an important class of porous materials for their amenability to design and the flexibility with which their pores can be functionalized. MOFs are extended porous structures and perfectly crystalline solids composed of transition metal ions or clusters that are linked by organic bridges, which form the main body of MOFs. Linkers are of utmost importance and play a vital role in determining the size of pores in the final framework. Functionalized pores can be predicted by the functional groups present on the linkers. MOFs with carboxylate and amine functionalities have potential applications in gas storage gas separation and purification, catalysis and drug delivery. In continuation and in order to advance the development of MOFs, we have designed and synthesized four organic linkers functionalized by crown ethers. Multi-step synthetic strategies have been applied which include alkylation, silylation, bromination, Suzuki coupling and Sonogashira cross coupling reactions. All the compounds were characterized by 1H and 13C NMR.

ISBN: 9781267620064Subjects--Topical Terms:

523952
Organic chemistry.

Synthesis and characterization of organic linkers functionalized by crown ethers for metal-organic frameworks.
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