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Hypervalent iodine reagents for tosy...

Klasen, Scott Clay.

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Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis./
作者:	Klasen, Scott Clay.
面頁冊數:	127 p.
附註:	Source: Masters Abstracts International, Volume: 55-02.
Contained By:	Masters Abstracts International55-02(E).
標題:	Organic chemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1601585
ISBN:	9781339135090

Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis.
Klasen, Scott Clay.

Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis. - 127 p.

Source: Masters Abstracts International, Volume: 55-02.

Thesis (M.S.)--University of Minnesota, 2015.

In recent years, organohypervalent iodine compounds have emerged as environmentally friendly and efficient reagents for various synthetically useful oxidative transformations. The purpose of this research is to take a closer look at newer five membered heterocyclic hypervalent iodine compounds similar to the hydroxy(tosyloxy)iodobenzene (HTIB) studied by G.F. Koser in the 1980's, which utilized different variations of iodobenzene with different functional groups in the para-position of a benzene ring in order to perform ligand transfer reactions. Utilizing Koser's framework new heterocyclic hypervalent iodine reagents have been synthesized using 2-iodobenzoic acid as well as other similar substrates as a starting material along with HTIB. Different variations of these heterocycles have been synthesized in order to analyze the structural and kinetic nature of these less studied derivatives and their overall reactivity for selective oxidations and tosyl-transfer reactions in organic synthesis.*.

ISBN: 9781339135090Subjects--Topical Terms:

523952
Organic chemistry.

Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis.
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245 1 0 $a Hypervalent iodine reagents for tosyl transfer reactions in organic synthesis.
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500 $a Source: Masters Abstracts International, Volume: 55-02.
500 $a Advisers: Viktor V. Zhdankin; Akira Yoshimura.
502 $a Thesis (M.S.)--University of Minnesota, 2015.
520 $a In recent years, organohypervalent iodine compounds have emerged as environmentally friendly and efficient reagents for various synthetically useful oxidative transformations. The purpose of this research is to take a closer look at newer five membered heterocyclic hypervalent iodine compounds similar to the hydroxy(tosyloxy)iodobenzene (HTIB) studied by G.F. Koser in the 1980's, which utilized different variations of iodobenzene with different functional groups in the para-position of a benzene ring in order to perform ligand transfer reactions. Utilizing Koser's framework new heterocyclic hypervalent iodine reagents have been synthesized using 2-iodobenzoic acid as well as other similar substrates as a starting material along with HTIB. Different variations of these heterocycles have been synthesized in order to analyze the structural and kinetic nature of these less studied derivatives and their overall reactivity for selective oxidations and tosyl-transfer reactions in organic synthesis.*.
520 $a *Please refer to dissertation for diagrams.
590 $a School code: 0130.
650 4 $a Organic chemistry. $3 523952
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