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Selective Hydrogenation of Acetylene...

Walker, Michael P.

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Selective Hydrogenation of Acetylene over Pd, Au, and PdAu Supported Nanoparticles.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Selective Hydrogenation of Acetylene over Pd, Au, and PdAu Supported Nanoparticles./
Author:	Walker, Michael P.
Description:	122 p.
Notes:	Source: Masters Abstracts International, Volume: 52-06.
Contained By:	Masters Abstracts International52-06(E).
Subject:	Chemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=MS26755
ISBN:	9780499267559

Selective Hydrogenation of Acetylene over Pd, Au, and PdAu Supported Nanoparticles.
Walker, Michael P.

Selective Hydrogenation of Acetylene over Pd, Au, and PdAu Supported Nanoparticles. - 122 p.

Source: Masters Abstracts International, Volume: 52-06.

Thesis (M.Chem.)--University of Ottawa (Canada), 2014.

This item must not be sold to any third party vendors.

The removal of trace amounts of acetylene in ethylene streams is a high-volume industrial process that must possess high selectivity of alkyne hydrogenation over hydrogenation of alkenes. Current technology uses metallic nanoparticles, typically palladium or platinum, for acetylene removal. However, problems arise due to the deactivation of the catalysts at high temperatures as well as low selectivities at high conversions.

ISBN: 9780499267559Subjects--Topical Terms:

516420
Chemistry.

Selective Hydrogenation of Acetylene over Pd, Au, and PdAu Supported Nanoparticles.
LDR:02103nmm a2200313 4500 001 2059542
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020 $a 9780499267559
035 $a (MiAaPQ)AAIMS26755
035 $a AAIMS26755
040 $a MiAaPQ $c MiAaPQ
100 1 $a Walker, Michael P. $3 3173625
245 1 0 $a Selective Hydrogenation of Acetylene over Pd, Au, and PdAu Supported Nanoparticles.
300 $a 122 p.
500 $a Source: Masters Abstracts International, Volume: 52-06.
500 $a Adviser: Abdelhamid Sayari.
502 $a Thesis (M.Chem.)--University of Ottawa (Canada), 2014.
506 $a This item must not be sold to any third party vendors.
506 $a This item must not be added to any third party search indexes.
520 $a The removal of trace amounts of acetylene in ethylene streams is a high-volume industrial process that must possess high selectivity of alkyne hydrogenation over hydrogenation of alkenes. Current technology uses metallic nanoparticles, typically palladium or platinum, for acetylene removal. However, problems arise due to the deactivation of the catalysts at high temperatures as well as low selectivities at high conversions.
520 $a Pore expanded MCM-41 is synthesized via a two-step strategy in which MCM-41 was prepared via cetyltrimethylammonium bromide (CTMABr) followed by the hydrothermal treatment with N,N-dimethyldecylamine (DMDA). This material was washed with ethanol to remove DMDA, or calcined to remove both surfactants. PE-MCM-41 based materials were impregnated with palladium, gold, and palladium-gold nanoparticles. The removal of DMDA had an effect on both the conversion and selectivity, in which they were found to drop significantly. However, by using the bimetallic PdAu catalysts, higher selectivity could be achieved due to increased electron density.
590 $a School code: 0918.
650 4 $a Chemistry. $3 516420
650 4 $a Nanoscience. $3 587832
690 $a 0485
690 $a 0565
710 2 $a University of Ottawa (Canada). $b Chemistry. $3 2092072
773 0 $t Masters Abstracts International $g 52-06(E).
790 $a 0918
791 $a M.Chem.
792 $a 2014
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=MS26755