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Cross-Conjugated Moieties as Design ...

Rawal, Meghana.

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Cross-Conjugated Moieties as Design Motifs for a Class of Novel Electro-Optic Chromophores.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Cross-Conjugated Moieties as Design Motifs for a Class of Novel Electro-Optic Chromophores./
作者:	Rawal, Meghana.
面頁冊數:	210 p.
附註:	Source: Dissertation Abstracts International, Volume: 75-08(E), Section: B.
Contained By:	Dissertation Abstracts International75-08B(E).
標題:	Chemistry, Molecular. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3618321
ISBN:	9781303865435

Cross-Conjugated Moieties as Design Motifs for a Class of Novel Electro-Optic Chromophores.
Rawal, Meghana.

Cross-Conjugated Moieties as Design Motifs for a Class of Novel Electro-Optic Chromophores. - 210 p.

Source: Dissertation Abstracts International, Volume: 75-08(E), Section: B.

Thesis (Ph.D.)--University of Washington, 2014.

Organic electro-optic materials are at the forefront of current photonics applications that enable high speed data transmission, micro-scale sensors, and terahertz applications. Typically linearly conjugated push-pull type chromophores are the primary molecules of choice for various second and third order non-linear optical (NLO) applications. However, intra-molecular charge transfer responsible for many NLO properties can take place in molecules through other means such as sigma-conjugation, cross-conjugation and omniconjugation as well. In Chapter 2 a study of electronic transitions, excited states and first hyperpolarizibility (beta) of a series of molecules with a cross-conjugated bridge functionalized with a dialkylaminobenzene donor on one end and varying strength acceptors on the other end is reported. A lowered excited state dipole moment compared to the ground state dipole was indicated for an asymmetric cross-conjugated molecule with a relatively stronger acceptor confirming that the cross-conjugated bridge does in fact break the over-all molecular dipole into two constituent parts. The primary charge-transfer transition was, however still identified to occur from the donor across the cross-conjugated bridge to the acceptor. X-ray diffraction (XRD) found the molecules to be twisted significantly resulting in further isolation of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO). This reduced overlap of the HOMO and the LUMO in cross-conjugated systems may in fact enable independent modulation of donor and acceptor strengths while minimizing unfavorable effects on electronic transitions and dipole moments. Comparison of hyperpolarizabilities with a control molecule found that cross-conjugation did not completely diminish beta.

ISBN: 9781303865435Subjects--Topical Terms:

1676084
Chemistry, Molecular.

Cross-Conjugated Moieties as Design Motifs for a Class of Novel Electro-Optic Chromophores.
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245 1 0 $a Cross-Conjugated Moieties as Design Motifs for a Class of Novel Electro-Optic Chromophores.
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500 $a Source: Dissertation Abstracts International, Volume: 75-08(E), Section: B.
500 $a Adviser: Larry R. Dalton.
502 $a Thesis (Ph.D.)--University of Washington, 2014.
520 $a Organic electro-optic materials are at the forefront of current photonics applications that enable high speed data transmission, micro-scale sensors, and terahertz applications. Typically linearly conjugated push-pull type chromophores are the primary molecules of choice for various second and third order non-linear optical (NLO) applications. However, intra-molecular charge transfer responsible for many NLO properties can take place in molecules through other means such as sigma-conjugation, cross-conjugation and omniconjugation as well. In Chapter 2 a study of electronic transitions, excited states and first hyperpolarizibility (beta) of a series of molecules with a cross-conjugated bridge functionalized with a dialkylaminobenzene donor on one end and varying strength acceptors on the other end is reported. A lowered excited state dipole moment compared to the ground state dipole was indicated for an asymmetric cross-conjugated molecule with a relatively stronger acceptor confirming that the cross-conjugated bridge does in fact break the over-all molecular dipole into two constituent parts. The primary charge-transfer transition was, however still identified to occur from the donor across the cross-conjugated bridge to the acceptor. X-ray diffraction (XRD) found the molecules to be twisted significantly resulting in further isolation of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO). This reduced overlap of the HOMO and the LUMO in cross-conjugated systems may in fact enable independent modulation of donor and acceptor strengths while minimizing unfavorable effects on electronic transitions and dipole moments. Comparison of hyperpolarizabilities with a control molecule found that cross-conjugation did not completely diminish beta.
520 $a In Chapter 3, a tricyanopyrroline (TCP) type acceptor was substituted on the cross-conjugated molecules to observe the effects of cross-conjugation on the molecular structure, the ground and excited states of the molecules and consequently beta. Through XRD the cross-conjugated motif was found to be perpendicular to the conjugated TCP chromophore and the TCP acceptor was twisted out of plane from the donor despite being conjugated to the donor. Further the aromatic substituents on the cross-conjugated side group were found to interact with each other influencing crystal packing. The dihedral twist and the aromatic interactions are indicated as the cause of reduced aggregation behavior. Hyper-Raleigh scattering measurements found the compounds to have beta values comparable to their fully conjugated control molecules. The beta values were expected to be influenced by the cross-conjugated side groups acting as auxiliary acceptors as well as by the dihedral twist observed in these molecules resulting in larger spatial isolation between the HOMO and LUMO.
520 $a In conclusion the use of a cross-conjugated motif by itself (Chapter 2) and in conjunction with a conjugated chromophore (Chapter 3) was studied and found to be useful towards affecting aggregation, solubility and hyperpolarizability of NLO chromophores.
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