東華大學圖書館 |

語系: 繁體中文

說明(常見問題)

回圖書館首頁

手機版館藏查詢

登入

回首頁

切換: 標籤 | MARC模式 | ISBD

Enzyme-Inspired Metal-Organic Framew...

Roberts, John Michael.

FindBook

Google Book

Amazon

博客來

Enzyme-Inspired Metal-Organic Framework Catalysts.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Enzyme-Inspired Metal-Organic Framework Catalysts./
作者:	Roberts, John Michael.
面頁冊數:	173 p.
附註:	Source: Dissertation Abstracts International, Volume: 73-09(E), Section: B.
Contained By:	Dissertation Abstracts International73-09B(E).
標題:	Chemistry, General. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3508345
ISBN:	9781267340467

Enzyme-Inspired Metal-Organic Framework Catalysts.
Roberts, John Michael.

Enzyme-Inspired Metal-Organic Framework Catalysts. - 173 p.

Source: Dissertation Abstracts International, Volume: 73-09(E), Section: B.

Thesis (Ph.D.)--Northwestern University, 2012.

In the past two decades, metal-organic frameworks (MOFs), a promising class of coordination polymer materials, have been developed and applied as gas separation/storage materials, drug delivery vehicles, light-harvesting material, and catalysts. MOF materials are attractive candidates for the listed applications due to their permanent microporosity and tunable nature. This dissertation describes the design, synthesis, and application of MOF catalyst materials that incorporate N-Heterocyclic carbene (NHC) and hydrogen-bond donor (HBD) catalysts. Libraries of novel MOF struts that emulate well-precedented homogeneous catalysts and act as NHC and HBD catalysts have been synthesized. These struts have been used to synthesize a series of MOF catalyst materials. Among the MOFs synthesized is the first microporous MOF to incorporate azolium salts, a series of unusual zwitterionic MOFs, analogs of known MOF materials, and novel MOF that incorporate HBD catalysts.

ISBN: 9781267340467Subjects--Topical Terms:

1021807
Chemistry, General.

Enzyme-Inspired Metal-Organic Framework Catalysts.
LDR:02221nam a2200313 4500 001 1967974
005 20141121133051.5
008 150210s2012 ||||||||||||||||| ||eng d
020 $a 9781267340467
035 $a (MiAaPQ)AAI3508345
035 $a AAI3508345
040 $a MiAaPQ $c MiAaPQ
100 1 $a Roberts, John Michael. $3 2105071
245 1 0 $a Enzyme-Inspired Metal-Organic Framework Catalysts.
300 $a 173 p.
500 $a Source: Dissertation Abstracts International, Volume: 73-09(E), Section: B.
500 $a Adviser: Karl A. Scheidt.
502 $a Thesis (Ph.D.)--Northwestern University, 2012.
520 $a In the past two decades, metal-organic frameworks (MOFs), a promising class of coordination polymer materials, have been developed and applied as gas separation/storage materials, drug delivery vehicles, light-harvesting material, and catalysts. MOF materials are attractive candidates for the listed applications due to their permanent microporosity and tunable nature. This dissertation describes the design, synthesis, and application of MOF catalyst materials that incorporate N-Heterocyclic carbene (NHC) and hydrogen-bond donor (HBD) catalysts. Libraries of novel MOF struts that emulate well-precedented homogeneous catalysts and act as NHC and HBD catalysts have been synthesized. These struts have been used to synthesize a series of MOF catalyst materials. Among the MOFs synthesized is the first microporous MOF to incorporate azolium salts, a series of unusual zwitterionic MOFs, analogs of known MOF materials, and novel MOF that incorporate HBD catalysts.
520 $a Azolium MOFs CuMAFc and NU-303 have been applied as gas storage and gas separation materials respectively. MOFs NU-501-504 demonstrate catenation control by rational ligand design, and NU-601 was shown to be a novel heterogeneous HBD catalyst that is more reactive than a related homogeneous catalyst, size selective, robust, and reusable.
590 $a School code: 0163.
650 4 $a Chemistry, General. $3 1021807
650 4 $a Chemistry, Organic. $3 516206
650 4 $a Chemistry, Inorganic. $3 517253
650 4 $a Chemistry, Biochemistry. $3 1017722
690 $a 0485
690 $a 0490
690 $a 0488
690 $a 0487
710 2 $a Northwestern University. $b Chemistry. $3 1030729
773 0 $t Dissertation Abstracts International $g 73-09B(E).
790 $a 0163
791 $a Ph.D.
792 $a 2012
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3508345