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Enhanced structural support of metal...

Das, Sanjit.

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Enhanced structural support of metal sites as nodes in metalorganic frameworks compared to metal complexes.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Enhanced structural support of metal sites as nodes in metalorganic frameworks compared to metal complexes./
作者:	Das, Sanjit.
面頁冊數:	47 p.
附註:	Source: Masters Abstracts International, Volume: 52-01.
Contained By:	Masters Abstracts International52-01(E).
標題:	Chemistry, Biochemistry. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1539754
ISBN:	9781303157974

Enhanced structural support of metal sites as nodes in metalorganic frameworks compared to metal complexes.
Das, Sanjit.

Enhanced structural support of metal sites as nodes in metalorganic frameworks compared to metal complexes. - 47 p.

Source: Masters Abstracts International, Volume: 52-01.

Thesis (M.S.)--Utah State University, 2013.

Metal-organic frameworks are a new class of crystalline, porous solid-state materials with metal ions periodically linked by organic linkers. This gives rise to one-, two- or three-dimensional structures. Here, we compare the stability of similar metal sites toward external ligand (solvent) induced disruption of the coordination environment in metal complexes and in metal-organic frameworks. Our experimental results show that a metal site as node of a metal-organic framework retains much higher stability compared to a similar metal site in a metal complex.

ISBN: 9781303157974Subjects--Topical Terms:

1017722
Chemistry, Biochemistry.

Enhanced structural support of metal sites as nodes in metalorganic frameworks compared to metal complexes.
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500 $a Adviser: Siddhartha Das.
502 $a Thesis (M.S.)--Utah State University, 2013.
520 $a Metal-organic frameworks are a new class of crystalline, porous solid-state materials with metal ions periodically linked by organic linkers. This gives rise to one-, two- or three-dimensional structures. Here, we compare the stability of similar metal sites toward external ligand (solvent) induced disruption of the coordination environment in metal complexes and in metal-organic frameworks. Our experimental results show that a metal site as node of a metal-organic framework retains much higher stability compared to a similar metal site in a metal complex.
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