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Pericyclic and cationic routes to no...

Thamatam, Rajesh.

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Pericyclic and cationic routes to novel organic structures.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Pericyclic and cationic routes to novel organic structures./
作者:	Thamatam, Rajesh.
面頁冊數:	269 p.
附註:	Source: Dissertation Abstracts International, Volume: 75-06(E), Section: B.
Contained By:	Dissertation Abstracts International75-06B(E).
標題:	Chemistry, General. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3579694
ISBN:	9781303790126

Pericyclic and cationic routes to novel organic structures.
Thamatam, Rajesh.

Pericyclic and cationic routes to novel organic structures. - 269 p.

Source: Dissertation Abstracts International, Volume: 75-06(E), Section: B.

Thesis (Ph.D.)--University of New Hampshire, 2013.

The term "dehydropericyclic" reaction is a new term coined in our research group. Pericyclic reactions usually involve stable reactants and products, whereas dehydropericyclic reactions are conceptually derived from pericyclic reactions by systematic removal of hydrogen atom pairs. The dehydropericyclic concept provides a straightforward approach for inventing new chemical reactions, especially routes to reactive intermediates, and for fitting other known processes into a broader framework. Dehydropericyclic routes to acenes by benzene fused bisallene electrocyclization was attempted.

ISBN: 9781303790126Subjects--Topical Terms:

1021807
Chemistry, General.

Pericyclic and cationic routes to novel organic structures.
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100 1 $a Thamatam, Rajesh. $3 2104973
245 1 0 $a Pericyclic and cationic routes to novel organic structures.
300 $a 269 p.
500 $a Source: Dissertation Abstracts International, Volume: 75-06(E), Section: B.
500 $a Adviser: Richard P. Johnson.
502 $a Thesis (Ph.D.)--University of New Hampshire, 2013.
520 $a The term "dehydropericyclic" reaction is a new term coined in our research group. Pericyclic reactions usually involve stable reactants and products, whereas dehydropericyclic reactions are conceptually derived from pericyclic reactions by systematic removal of hydrogen atom pairs. The dehydropericyclic concept provides a straightforward approach for inventing new chemical reactions, especially routes to reactive intermediates, and for fitting other known processes into a broader framework. Dehydropericyclic routes to acenes by benzene fused bisallene electrocyclization was attempted.
520 $a Chloroacrylic acid was discovered as a simple and versatile acetylene equivalent in Diels-Alder reactions. The scope and generality of this methodology has been exemplified by synthesizing a variety of acenobarrelenes. With our recent entry into the arena of cationic reactions, a highly efficient and scalable route to quaterrylene has been demonstrated. A novel solution-phase NMR technique has been developed to characterize insoluble polycyclic aromatic hydrocarbons as oxidative dication.
590 $a School code: 0141.
650 4 $a Chemistry, General. $3 1021807
690 $a 0485
710 2 $a University of New Hampshire. $3 1017788
773 0 $t Dissertation Abstracts International $g 75-06B(E).
790 $a 0141
791 $a Ph.D.
792 $a 2013
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3579694