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Developing new methods to functional...

Bischof, Steven Michael.

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Developing new methods to functionalize carbon-hydrogen bonds using a carbon-hydrogen activation/M-R functionalization approach.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Developing new methods to functionalize carbon-hydrogen bonds using a carbon-hydrogen activation/M-R functionalization approach./
作者:	Bischof, Steven Michael.
面頁冊數:	459 p.
附註:	Source: Dissertation Abstracts International, Volume: 74-04(E), Section: B.
Contained By:	Dissertation Abstracts International74-04B(E).
標題:	Chemistry, Inorganic. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3533734
ISBN:	9781267789815

Developing new methods to functionalize carbon-hydrogen bonds using a carbon-hydrogen activation/M-R functionalization approach.
Bischof, Steven Michael.

Developing new methods to functionalize carbon-hydrogen bonds using a carbon-hydrogen activation/M-R functionalization approach. - 459 p.

Source: Dissertation Abstracts International, Volume: 74-04(E), Section: B.

Thesis (Ph.D.)--The Scripps Research Institute, 2012.

The conversion of hydrocarbon resources (oil and natural gas) to useful products constitutes a major portion of industrial chemistry; wherein, the products of such processes are utilized in the manufacture of materials, commodity chemicals, and pharmaceuticals. One possible method for overcoming this challenge is the design of new catalysts that operate via the C-H activation reaction coupled to an efficient M-R functionalization using transition metal catalysts. However, very few efficient C-H functionalization catalysts have been reported in the literature. The development of new methods to functionalize M-R intermediates and their coupling to C-H activation may meet this challenge.

ISBN: 9781267789815Subjects--Topical Terms:

517253
Chemistry, Inorganic.

Developing new methods to functionalize carbon-hydrogen bonds using a carbon-hydrogen activation/M-R functionalization approach.
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245 1 0 $a Developing new methods to functionalize carbon-hydrogen bonds using a carbon-hydrogen activation/M-R functionalization approach.
300 $a 459 p.
500 $a Source: Dissertation Abstracts International, Volume: 74-04(E), Section: B.
502 $a Thesis (Ph.D.)--The Scripps Research Institute, 2012.
520 $a The conversion of hydrocarbon resources (oil and natural gas) to useful products constitutes a major portion of industrial chemistry; wherein, the products of such processes are utilized in the manufacture of materials, commodity chemicals, and pharmaceuticals. One possible method for overcoming this challenge is the design of new catalysts that operate via the C-H activation reaction coupled to an efficient M-R functionalization using transition metal catalysts. However, very few efficient C-H functionalization catalysts have been reported in the literature. The development of new methods to functionalize M-R intermediates and their coupling to C-H activation may meet this challenge.
520 $a This thesis presents work focused on two core areas related to C-H bond functionalization, C-H activation and M-R functionalization. C-H activation involves the formation of an activated of metal-carbon intermediate by scission of a hydrocarbon C-H bond. This is followed by functionalization of the incipient metal-carbon intermediate to generate C-X bonds. The concepts related to choosing such a two-step, C-H activation/M-R functionalization, approach are presented in Chapter 1.
520 $a Following chapters focus on independent study of C-H activation and M-R functionalization reactions, with a final emphasis on combining working M-R functionalization reactions to known C-H activation catalysts to complete the catalytic cycle. Chapter 2 focuses on Baeyer-Villiger and related functionalization reactions of an aryl-rheniumtrioxide complex. Work on M-R functionalization reactions is extended in Chapter 3 with a study on low oxidation state Re-CH3 compounds for oxy-functionalization reactions. Examination of an iridium catalyst that undergoes extraordinarily facile C-H activation and the mechanistic basis for the observed catalytic rates is presented in Chapter 4. Chapter 5 extends our examination on the C-H activation reaction using iridium and rhodium catalysts and finds that both arenes and alkanes are activated. Most significantly, oxy-functionalization of benzene is observed in the presence of CuII salts using either family of catalysts. Finally, Chapter 6 makes concluding remarks on this work and what lies in store for the future.
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