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Effect of silver nanoparticles on th...

Olumoroti, Akinloluwa T.

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Effect of silver nanoparticles on the fluorescence of Pb2+ and compositional dependence of Sm3+ fluorescence in borate glasses.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Effect of silver nanoparticles on the fluorescence of Pb2+ and compositional dependence of Sm3+ fluorescence in borate glasses./
Author:	Olumoroti, Akinloluwa T.
Description:	119 p.
Notes:	Source: Masters Abstracts International, Volume: 51-06.
Contained By:	Masters Abstracts International51-06(E).
Subject:	Physics, Atomic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1538804
ISBN:	9781303128059

Effect of silver nanoparticles on the fluorescence of Pb2+ and compositional dependence of Sm3+ fluorescence in borate glasses.
Olumoroti, Akinloluwa T.

Effect of silver nanoparticles on the fluorescence of Pb2+ and compositional dependence of Sm3+ fluorescence in borate glasses. - 119 p.

Source: Masters Abstracts International, Volume: 51-06.

Thesis (M.S.)--Western Illinois University, 2013.

Borate glasses have been widely studied due to their good optical and mechanical properties. Lead and bismuth (PbO/Bi2O 3:B2O3) borate glasses belong to a family of heavy metal oxide (HMO) glasses which are well known to be chemically durable, stable against atmospheric moisture, have low melting temperatures and good corrosion resistance. The first part of this work deals with lead borate glasses with silver nanoparticles (NPs) introduced into the glass matrix. Transmission electron microscopy characterization is done to verify the nucleation of NPs. Fluorescence and optical absorption experiments are then carried out after different heat treatment duration to investigate the influence of silver NPs on the optical properties of lead (Pb2+) by comparing with a glass sample without silver NPs. Optical absorption experiments show that a well-defined surface plasmon resonance (SPR) peak due to Ag NPs can be observed only for samples that were annealed for 36 hrs. Pb2+ fluorescence spectra reveal that the presence of silver NPs creates new emission centers for Pb2+ ions by altering their chemical environment.

ISBN: 9781303128059Subjects--Topical Terms:

1029235
Physics, Atomic.

Effect of silver nanoparticles on the fluorescence of Pb2+ and compositional dependence of Sm3+ fluorescence in borate glasses.
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020 $a 9781303128059
035 $a (MiAaPQ)AAI1538804
035 $a AAI1538804
040 $a MiAaPQ $c MiAaPQ
100 1 $a Olumoroti, Akinloluwa T. $3 2096650
245 1 0 $a Effect of silver nanoparticles on the fluorescence of Pb2+ and compositional dependence of Sm3+ fluorescence in borate glasses.
300 $a 119 p.
500 $a Source: Masters Abstracts International, Volume: 51-06.
500 $a Advisers: Panakkattu K. Babu; Saisudha B. Mallur.
502 $a Thesis (M.S.)--Western Illinois University, 2013.
520 $a Borate glasses have been widely studied due to their good optical and mechanical properties. Lead and bismuth (PbO/Bi2O 3:B2O3) borate glasses belong to a family of heavy metal oxide (HMO) glasses which are well known to be chemically durable, stable against atmospheric moisture, have low melting temperatures and good corrosion resistance. The first part of this work deals with lead borate glasses with silver nanoparticles (NPs) introduced into the glass matrix. Transmission electron microscopy characterization is done to verify the nucleation of NPs. Fluorescence and optical absorption experiments are then carried out after different heat treatment duration to investigate the influence of silver NPs on the optical properties of lead (Pb2+) by comparing with a glass sample without silver NPs. Optical absorption experiments show that a well-defined surface plasmon resonance (SPR) peak due to Ag NPs can be observed only for samples that were annealed for 36 hrs. Pb2+ fluorescence spectra reveal that the presence of silver NPs creates new emission centers for Pb2+ ions by altering their chemical environment.
520 $a The second part of the work involves the use of samarium (a rare earth ion) as a dopant in lead and bismuth borate glasses. The concentration of samarium (Sm3+) is fixed and the base glass composition is varied. The goal is to investigate the compositional dependence of optical properties of samarium in the base glass (PbO/Bi2O3:B 2O3). Optical absorption spectra have been collected and the oscillator strength of each transition - including the hypersensitive - is obtained. The Optical absorption edge is found to shift toward lower energies with increasing PbO/Bi2O3 concentration. Both the oscillator strength and the peak position of the hypersensitive transition show significant variation with glass composition. Strong interaction between Sm3+ ions and Pb2+/Bi3+ ions can also be seen from the variations in the fluorescence emission properties of Sm3+ as a function of base glass composition.
520 $a Studying the variation of these optical properties will help to create the optimum rare-earth ion-host configuration for possible technological applications. This is the thrust of our future investigations of these glass systems.
520 $a Keywords: Borate glasses, nanoparticles, fluorescence, transmission electron microscopy, optical absorption, surface plasmon resonance, rare-earth (RE) ions, oscillator strength, hypersensitive transition (HST).
590 $a School code: 6012.
650 4 $a Physics, Atomic. $3 1029235
650 4 $a Physics, Molecular. $3 1018648
690 $a 0748
690 $a 0609
710 2 $a Western Illinois University. $b Physics. $3 2096651
773 0 $t Masters Abstracts International $g 51-06(E).
790 $a 6012
791 $a M.S.
792 $a 2013
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1538804