東華大學圖書館 |

Language: English

Help

回圖書館首頁

手機版館藏查詢

Back

Switch To: Labeled | MARC Mode | ISBD

Metal-mediated cross-coupling of act...

Still, Raymond S.

Linked to FindBook

Google Book

Amazon

博客來

Metal-mediated cross-coupling of activated enol-triflates and enol-carbamates.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Metal-mediated cross-coupling of activated enol-triflates and enol-carbamates./
Author:	Still, Raymond S.
Description:	120 p.
Notes:	Source: Masters Abstracts International, Volume: 51-06.
Contained By:	Masters Abstracts International51-06(E).
Subject:	Chemistry, General. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1538405
ISBN:	9781303114458

Metal-mediated cross-coupling of activated enol-triflates and enol-carbamates.
Still, Raymond S.

Metal-mediated cross-coupling of activated enol-triflates and enol-carbamates. - 120 p.

Source: Masters Abstracts International, Volume: 51-06.

Thesis (M.S.)--The University of Texas at San Antonio, 2013.

Two projects are discussed: The regioselective synthesis of pyrazoles and the stereoselective synthesis and use of enol carbamate esters. First, pyrazoles are generated by an initial palladium-catalyzed cross-coupling of stereodefined enol trilfate esters with diazoacetates, followed by a thermally induced 6pi-electrocyclization. Then, conditions to generate (E )-vinyl carbamates are developed, and literature preparations are used to synthesize (Z)-vinyl carbamates. Development of methodology to cross-couple these stereodefined enol carbamates with alkyl Grignard reagents to produce tri-and tetrasubstituted olefins using a Fe(III) precatalyst is presented.

ISBN: 9781303114458Subjects--Topical Terms:

1021807
Chemistry, General.

Metal-mediated cross-coupling of activated enol-triflates and enol-carbamates.
LDR:01525nam a2200277 4500 001 1960884
005 20140701144838.5
008 150210s2013 ||||||||||||||||| ||eng d
020 $a 9781303114458
035 $a (MiAaPQ)AAI1538405
035 $a AAI1538405
040 $a MiAaPQ $c MiAaPQ
100 1 $a Still, Raymond S. $3 2096649
245 1 0 $a Metal-mediated cross-coupling of activated enol-triflates and enol-carbamates.
300 $a 120 p.
500 $a Source: Masters Abstracts International, Volume: 51-06.
500 $a Adviser: Doug E. Frantz.
502 $a Thesis (M.S.)--The University of Texas at San Antonio, 2013.
520 $a Two projects are discussed: The regioselective synthesis of pyrazoles and the stereoselective synthesis and use of enol carbamate esters. First, pyrazoles are generated by an initial palladium-catalyzed cross-coupling of stereodefined enol trilfate esters with diazoacetates, followed by a thermally induced 6pi-electrocyclization. Then, conditions to generate (E )-vinyl carbamates are developed, and literature preparations are used to synthesize (Z)-vinyl carbamates. Development of methodology to cross-couple these stereodefined enol carbamates with alkyl Grignard reagents to produce tri-and tetrasubstituted olefins using a Fe(III) precatalyst is presented.
590 $a School code: 1283.
650 4 $a Chemistry, General. $3 1021807
650 4 $a Chemistry, Organic. $3 516206
690 $a 0485
690 $a 0490
710 2 $a The University of Texas at San Antonio. $b Chemistry. $3 1043223
773 0 $t Masters Abstracts International $g 51-06(E).
790 $a 1283
791 $a M.S.
792 $a 2013
793 $a English
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1538405