東華大學圖書館 |

Language: English

Help

回圖書館首頁

手機版館藏查詢

Back

Switch To: Labeled | MARC Mode | ISBD

Analytical methods for solid polymer...

Geiculescu, Olt Emil.

Linked to FindBook

Google Book

Amazon

博客來

Analytical methods for solid polymer electrolytes used in rechargeable lithium batteries.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Analytical methods for solid polymer electrolytes used in rechargeable lithium batteries./
Author:	Geiculescu, Olt Emil.
Description:	267 p.
Notes:	Source: Dissertation Abstracts International, Volume: 65-03, Section: B, page: 1296.
Contained By:	Dissertation Abstracts International65-03B.
Subject:	Chemistry, Analytical. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3125468
ISBN:	0496727575

Analytical methods for solid polymer electrolytes used in rechargeable lithium batteries.
Geiculescu, Olt Emil.

Analytical methods for solid polymer electrolytes used in rechargeable lithium batteries. - 267 p.

Source: Dissertation Abstracts International, Volume: 65-03, Section: B, page: 1296.

Thesis (Ph.D.)--Clemson University, 2004.

Novel lithium salts synthesized at Clemson by Dr. DesMarteau's research group have been tested as possible candidates for preparing solid polymer electrolytes (SPE) to be used in rechargeable lithium batteries. One such series consisted of seven new dilithium salts with structures similar to that of lithium bis[(trifluoromethyl)sulfonyl] imide, or LiTFSI, which is the most used standard salt in the field of lithium polymer batteries. It has one of the highest ionic conductivities known when incorporated into polyether-based SPEs, it's safe, but it has a corrosive effect upon the Al or Ni collectors of a battery. Another series consisted of polyanions, mainly oligoanions, with structures similar to that of LiTFSI, in polyether hosts. The work focused especially on preparation of SPEs from the dilithium salts in a high-Mw poly(ethylene oxide) (PEO) or cross-linked low-M w poly(ethylene glycol) (PEG) host, and on the structural, thermal and electrochemical characterization of these SPEs. Also, the effect of ceramic nano-fillers (fumed silica) upon conductivity was explored for several of the new salts.

ISBN: 0496727575Subjects--Topical Terms:

586156
Chemistry, Analytical.

Analytical methods for solid polymer electrolytes used in rechargeable lithium batteries.
LDR:02618nmm 2200313 4500 001 1847392
005 20051108094520.5
008 130614s2004 eng d
020 $a 0496727575
035 $a (UnM)AAI3125468
035 $a AAI3125468
040 $a UnM $c UnM
100 1 $a Geiculescu, Olt Emil. $3 1935441
245 1 0 $a Analytical methods for solid polymer electrolytes used in rechargeable lithium batteries.
300 $a 267 p.
500 $a Source: Dissertation Abstracts International, Volume: 65-03, Section: B, page: 1296.
500 $a Adviser: Stephen E. Creager.
502 $a Thesis (Ph.D.)--Clemson University, 2004.
520 $a Novel lithium salts synthesized at Clemson by Dr. DesMarteau's research group have been tested as possible candidates for preparing solid polymer electrolytes (SPE) to be used in rechargeable lithium batteries. One such series consisted of seven new dilithium salts with structures similar to that of lithium bis[(trifluoromethyl)sulfonyl] imide, or LiTFSI, which is the most used standard salt in the field of lithium polymer batteries. It has one of the highest ionic conductivities known when incorporated into polyether-based SPEs, it's safe, but it has a corrosive effect upon the Al or Ni collectors of a battery. Another series consisted of polyanions, mainly oligoanions, with structures similar to that of LiTFSI, in polyether hosts. The work focused especially on preparation of SPEs from the dilithium salts in a high-Mw poly(ethylene oxide) (PEO) or cross-linked low-M w poly(ethylene glycol) (PEG) host, and on the structural, thermal and electrochemical characterization of these SPEs. Also, the effect of ceramic nano-fillers (fumed silica) upon conductivity was explored for several of the new salts.
520 $a The search for suitable salts to be incorporated in polymer electrolytes continued with new derivatives of lithium (perfluorovinylether)sulfonate coupled with either a partially fluorinated alcohol (monolithium series) or a partially fluorinated diol (dilithium series). Again, high-Mw PEO was used as the polymer host.
520 $a SPEs characterization was accomplished using thermal methods (DSC), 1H and 19F NMR, X-ray diffraction and various electrochemical techniques such as: electrochemical impedance spectroscopy (EIS) and galvanostatic polarization.
590 $a School code: 0050.
650 4 $a Chemistry, Analytical. $3 586156
650 4 $a Chemistry, Polymer. $3 1018428
650 4 $a Engineering, Electronics and Electrical. $3 626636
690 $a 0486
690 $a 0495
690 $a 0544
710 2 0 $a Clemson University. $3 997173
773 0 $t Dissertation Abstracts International $g 65-03B.
790 1 0 $a Creager, Stephen E., $e advisor
790 $a 0050
791 $a Ph.D.
792 $a 2004
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3125468