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Thermodynamic and kinetic study on i...

Huang, Mianliang.

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Thermodynamic and kinetic study on intermetallic compounds palladium-indium and tripalladium-indium: Bulk and thin film cases.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Thermodynamic and kinetic study on intermetallic compounds palladium-indium and tripalladium-indium: Bulk and thin film cases./
作者:	Huang, Mianliang.
面頁冊數:	192 p.
附註:	Source: Dissertation Abstracts International, Volume: 65-04, Section: B, page: 2067.
Contained By:	Dissertation Abstracts International65-04B.
標題:	Engineering, Metallurgy. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3127973
ISBN:	0496752366

Thermodynamic and kinetic study on intermetallic compounds palladium-indium and tripalladium-indium: Bulk and thin film cases.
Huang, Mianliang.

Thermodynamic and kinetic study on intermetallic compounds palladium-indium and tripalladium-indium: Bulk and thin film cases. - 192 p.

Source: Dissertation Abstracts International, Volume: 65-04, Section: B, page: 2067.

Thesis (Ph.D.)--The University of Wisconsin - Madison, 2004.

I have thermodynamically and kinetically studied the compounds PdIn and Pd3In, which including experimental investigation and thermodynamic modeling of the In-Pd binary system, diffusion in the bulk B2 compound PdIn, grain growth in nanoscale PdIn thin films, and phase transformation in Pd 3In of both deformed alloys and sputter deposited thin films.

ISBN: 0496752366Subjects--Topical Terms:

1023648
Engineering, Metallurgy.

Thermodynamic and kinetic study on intermetallic compounds palladium-indium and tripalladium-indium: Bulk and thin film cases.
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100 1 $a Huang, Mianliang. $3 1927720
245 1 0 $a Thermodynamic and kinetic study on intermetallic compounds palladium-indium and tripalladium-indium: Bulk and thin film cases.
300 $a 192 p.
500 $a Source: Dissertation Abstracts International, Volume: 65-04, Section: B, page: 2067.
500 $a Supervisor: Y. Austin Chang.
502 $a Thesis (Ph.D.)--The University of Wisconsin - Madison, 2004.
520 $a I have thermodynamically and kinetically studied the compounds PdIn and Pd3In, which including experimental investigation and thermodynamic modeling of the In-Pd binary system, diffusion in the bulk B2 compound PdIn, grain growth in nanoscale PdIn thin films, and phase transformation in Pd 3In of both deformed alloys and sputter deposited thin films.
520 $a In the modeling of the In-Pd binary system, a self-consistent thermodynamic description of this system was obtained. The calculated phase boundaries and thermodynamic properties are in good agreement with the experimental data.
520 $a In the diffusion study on PdIn compounds, the interdiffusion coefficients at 700, 800, and 900°C were determined. The Kirkendall effect was observed from the marker movement and indicated that Pd diffused faster than In. Intrinsic diffusion coefficients of Pd and In were calculated by combing the interdiffusion coefficients and marker movements. The diffusion activation energies were estimated from the interdiffusion coefficients. The validity of Darken's equation was checked, indicating that the Darken's equation may not be applied to ordered intermetallic compounds with near triple defect structure such as PdIn.
520 $a Grain growth in sputter deposited PdIn thin films was investigated by annealing them in a differential scanning calorimeter (DSC) and characterized by transmission electron microscopy (TEM). The sequence of grain growth was found to begin with normal grain growth. Secondary grain growth was observed in late stages with a bimodal grain size distribution. The grain growth kinetics in PdIn thin films was analyzed.
520 $a In the last part, phase transformations in deformed Pd3In alloys and sputter deposited thin films were investigated using TEM, X-ray diffraction and DSC. TEM results show that the formation of microbands and twinning and sliding are the major deformation mechanisms. The crystal structure of the fully annealed Pd3In alloy and thin films was characterized as L60 ordered tetragonal structure and that of the fully deformed and as deposited ones as disordered face centered cubic structure. The kinetics of the phase transformation in the Pd3In thin films was simulated using the Johnson-Mehl-Avrami analysis and reasonable results were obtained. A comparison was carried out for the phase transformation in deformed Pd 3In alloys and sputter deposited films.
590 $a School code: 0262.
650 4 $a Engineering, Metallurgy. $3 1023648
650 4 $a Engineering, Materials Science. $3 1017759
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690 $a 0794
710 2 0 $a The University of Wisconsin - Madison. $3 626640
773 0 $t Dissertation Abstracts International $g 65-04B.
790 1 0 $a Chang, Y. Austin, $e advisor
790 $a 0262
791 $a Ph.D.
792 $a 2004
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3127973