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Watershed budgets of chloride and su...
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Shapiro, Josslyn B.
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Watershed budgets of chloride and sulfate as intergrators of ecosystem processes.
紀錄類型:
書目-電子資源 : Monograph/item
正題名/作者:
Watershed budgets of chloride and sulfate as intergrators of ecosystem processes./
作者:
Shapiro, Josslyn B.
面頁冊數:
269 p.
附註:
Source: Dissertation Abstracts International, Volume: 66-12, Section: B, page: 6507.
Contained By:
Dissertation Abstracts International66-12B.
標題:
Biogeochemistry. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3199580
ISBN:
9780542462795
Watershed budgets of chloride and sulfate as intergrators of ecosystem processes.
Shapiro, Josslyn B.
Watershed budgets of chloride and sulfate as intergrators of ecosystem processes.
- 269 p.
Source: Dissertation Abstracts International, Volume: 66-12, Section: B, page: 6507.
Thesis (Ph.D.)--Columbia University, 2006.
Cl- and SO42- budgets were developed for the Cascade Brook watershed within Black Rock Forest, in the Hudson Highlands, NY. Additionally, temporal trends in [H+], [NO3 -], [NH4+] and wet deposition were examined. Patterns in Cl- wet deposition indicated that sources in addition to sea-salt aerosols contribute ∼ 24% of mean annual Cl- wet deposition. These additional sources probably include HCl emissions from: (1) coal fired generating stations; (2) waste incineration; and, (3) HCl production from sea-salt dechlorination. Cl- export budgets for Cascade Brook yielded a Cl- export-to-Cl - wet deposition ratio of 3:1 indicating that there was at least one significant source in addition to wet deposition contributing Cl- to Cascade Brook. We conclude that additional Cl- sources contributing appreciable amounts to Cl- export include dry deposition and mineralization of soil organic matter.
ISBN: 9780542462795Subjects--Topical Terms:
545717
Biogeochemistry.
Watershed budgets of chloride and sulfate as intergrators of ecosystem processes.
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Cl- and SO42- budgets were developed for the Cascade Brook watershed within Black Rock Forest, in the Hudson Highlands, NY. Additionally, temporal trends in [H+], [NO3 -], [NH4+] and wet deposition were examined. Patterns in Cl- wet deposition indicated that sources in addition to sea-salt aerosols contribute ∼ 24% of mean annual Cl- wet deposition. These additional sources probably include HCl emissions from: (1) coal fired generating stations; (2) waste incineration; and, (3) HCl production from sea-salt dechlorination. Cl- export budgets for Cascade Brook yielded a Cl- export-to-Cl - wet deposition ratio of 3:1 indicating that there was at least one significant source in addition to wet deposition contributing Cl- to Cascade Brook. We conclude that additional Cl- sources contributing appreciable amounts to Cl- export include dry deposition and mineralization of soil organic matter.
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Decadal trends (1981-2003) in precipitation chemistry near Cascade Brook indicate that SO42- wet deposition decreased by ∼ 37%; a pattern consistent with decreases in SO2 emissions upwind of Black Rock Forest. In addition, SO42- wet deposition per unit area represented ∼ 20% of local and regional SO2 emissions, indicating that appreciable amounts of S were probably deposited locally as dry deposition or as wet and dry deposition at sites beyond the northeastern USA. An independent estimate of S dry deposition near Cascade Brook, derived using a dry deposition inferential technique, indicated that S dry deposition contributed 50% as much S as SO42--S wet deposition. Finally, temporal patterns in Cascade Brook SO42- surface water export indicated that: (1) appreciable amounts of S are probably stored temporarily within the Glycerine Hollow wetlands; and (2) the ∼ 2.8-3.1 ratio of SO42- export-to-SO4 2- wet deposition suggested that sources other than wet deposition contribute significant amounts of S to the watershed. Using a watershed mass balance approach, we estimate an upper limit for S dry deposition of 14-17 kg S ha-1 yr-1, which was ∼ 3.5-4.3 times the amount of S dry deposition derived from the inferential technique (4.0 kg S ha-1 yr-1).
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http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3199580
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