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Femtosecond non-degenerate four wave...

Prall, Bradley Scott.

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Femtosecond non-degenerate four wave mixing spectroscopy: The two color photon echo peak shift.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Femtosecond non-degenerate four wave mixing spectroscopy: The two color photon echo peak shift./
Author:	Prall, Bradley Scott.
Description:	221 p.
Notes:	Source: Dissertation Abstracts International, Volume: 66-08, Section: B, page: 4243.
Contained By:	Dissertation Abstracts International66-08B.
Subject:	Chemistry, Physical. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3187126
ISBN:	0542291312

Femtosecond non-degenerate four wave mixing spectroscopy: The two color photon echo peak shift.
Prall, Bradley Scott.

Femtosecond non-degenerate four wave mixing spectroscopy: The two color photon echo peak shift. - 221 p.

Source: Dissertation Abstracts International, Volume: 66-08, Section: B, page: 4243.

Thesis (Ph.D.)--University of California, Berkeley, 2005.

The couplings between multiple electronic states and electronic and nuclear coordinates are examined for condensed phase systems by femtosecond degenerate and non-degenerate four wave mixing. The two-color photon echo peak shift experiment is developed which allows measurement of the correlation between transition frequencies in two different spectral regions.

ISBN: 0542291312Subjects--Topical Terms:

560527
Chemistry, Physical.

Femtosecond non-degenerate four wave mixing spectroscopy: The two color photon echo peak shift.
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035 $a (UnM)AAI3187126
035 $a AAI3187126
040 $a UnM $c UnM
100 1 $a Prall, Bradley Scott. $3 1907612
245 1 0 $a Femtosecond non-degenerate four wave mixing spectroscopy: The two color photon echo peak shift.
300 $a 221 p.
500 $a Source: Dissertation Abstracts International, Volume: 66-08, Section: B, page: 4243.
500 $a Chair: Graham R. Fleming.
502 $a Thesis (Ph.D.)--University of California, Berkeley, 2005.
520 $a The couplings between multiple electronic states and electronic and nuclear coordinates are examined for condensed phase systems by femtosecond degenerate and non-degenerate four wave mixing. The two-color photon echo peak shift experiment is developed which allows measurement of the correlation between transition frequencies in two different spectral regions.
520 $a Two-color photon echo peak shift (2C3PEPS) experiments are used to study coupling between electronic states in the lutetium bisphthalocyanine anion, LuPc2-. Electronically induced mixing between exciton and charge resonance states leads to correlations in transition energies for the two observed transitions. This correlation generates non-zero 2C3PEPS which, when compared with 1C3PEPS, allows experimental determination of the degree of mixing, which was in good agreement with theoretical predictions.
520 $a By exploiting a coherently excited nuclear wavepacket, the nuclear dependence on the electronic mixing between exciton and charge resonance states is observed for LuPc2- along the excited nuclear coordinate. The change in mixing is manifested in pump probe spectroscopy as anti-correlated wave packet dynamics for the two dipole allowed states, and the nuclear coordinate dependence of the transition moment. Within the limit that all the dipole strength is derived from the exciton state, the change in mixing can be estimated.
520 $a 2C3PEPS is used to probe correlation between two different regions of the electronic spectrum of a chromophore. No correlation between the two spectral regions is observed at short times, but correlation appears owing to ultrafast solvent motion and the accompanying Stokes shift. A model for the spectral shift is proposed that incorporates a conditional probability distribution for transition frequencies in the two spectral regions. These results show that memory is partially conserved during the spectral diffusion process from the pump to the probe region.
520 $a Additional 2C3PEPS experiments exploring many spectral regions within the electronic transition band revealed that strongly coupled intramolecular vibrations generated correlations between different spectral regions. A single correlation function description of the solvation dynamics was insufficient to quantitatively describe the dynamics at all probe wavelengths indicating different dynamics in the ground and excited states, which implies a nonlinear dependence of the transition energy gap on the solvation coordinate.
590 $a School code: 0028.
650 4 $a Chemistry, Physical. $3 560527
650 4 $a Physics, Elementary Particles and High Energy. $3 1019488
690 $a 0494
690 $a 0798
710 2 0 $a University of California, Berkeley. $3 687832
773 0 $t Dissertation Abstracts International $g 66-08B.
790 1 0 $a Fleming, Graham R., $e advisor
790 $a 0028
791 $a Ph.D.
792 $a 2005
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3187126