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Applications of transition metal dop...

Hage, John Phillip.

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Applications of transition metal doped zeolites.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Applications of transition metal doped zeolites./
作者:	Hage, John Phillip.
面頁冊數:	246 p.
附註:	Source: Dissertation Abstracts International, Volume: 56-11, Section: B, page: 6106.
Contained By:	Dissertation Abstracts International56-11B.
標題:	Chemistry, Inorganic. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=9606794

Applications of transition metal doped zeolites.
Hage, John Phillip.

Applications of transition metal doped zeolites. - 246 p.

Source: Dissertation Abstracts International, Volume: 56-11, Section: B, page: 6106.

Thesis (Ph.D.)--University of Florida, 1994.

Zeolites provide an interesting medium for carrying out numerous chemical reactions. The focus of this work is the employment of transition metal doped zeolites for the reversible binding of oxygen and as catalysts in hydrocarbon oxidation.Subjects--Topical Terms:

517253
Chemistry, Inorganic.

Applications of transition metal doped zeolites.
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100 1 $a Hage, John Phillip. $3 1906918
245 1 0 $a Applications of transition metal doped zeolites.
300 $a 246 p.
500 $a Source: Dissertation Abstracts International, Volume: 56-11, Section: B, page: 6106.
500 $a Chairperson: Russell S. Drago.
502 $a Thesis (Ph.D.)--University of Florida, 1994.
520 $a Zeolites provide an interesting medium for carrying out numerous chemical reactions. The focus of this work is the employment of transition metal doped zeolites for the reversible binding of oxygen and as catalysts in hydrocarbon oxidation.
520 $a A large number of cobalt complexes consisting of a variety of ligands are known that reversibly bind oxygen. The main drawback to using these materials in catalysis or oxygen enrichment from air is that, in solution, dimerization and irreversible oxidation of the complexes occur. By synthesizing these complexes within the pores of a zeolite, these undesirable properties are eliminated. In this work, stable anionic cobalt(II)-cyanide complexes that reversibly bind oxygen have been synthesized inside zeolite Y. Synthetic methods developed to produce the maximum amount of these cobalt(II)-cyanide complexes inside zeolite Y are presented.
520 $a Industrial oxidation of hydrocarbons to useful oxygenated compounds is commercially important and carried out on a large scale. Often these oxidations involve high temperatures and pressures and lack selectivity. In this study, the oxidation of hydrocarbons with transition metal and transition metal complexes in various zeolites is investigated using hydroperoxides (hydrogen peroxide and t-butyl hydroperoxide) or oxygen. These reactions are carried out at a relatively low temperatures between 50-75 $\ sp\circ
590 $a School code: 0070.
650 4 $a Chemistry, Inorganic. $3 517253
690 $a 0488
710 2 0 $a University of Florida. $3 718949
773 0 $t Dissertation Abstracts International $g 56-11B.
790 1 0 $a Drago, Russell S., $e advisor
790 $a 0070
791 $a Ph.D.
792 $a 1994
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=9606794