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Enantioselective tandem cyclopropana...

Olson, Jeremy Price.

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Enantioselective tandem cyclopropanation/Cope rearrangement of heteroaryldiazoacetates and their applications in natural product synthesis.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Enantioselective tandem cyclopropanation/Cope rearrangement of heteroaryldiazoacetates and their applications in natural product synthesis./
Author:	Olson, Jeremy Price.
Description:	307 p.
Notes:	Source: Dissertation Abstracts International, Volume: 70-09, Section: B, page: 5521.
Contained By:	Dissertation Abstracts International70-09B.
Subject:	Chemistry, Organic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3372097
ISBN:	9781109343908

Enantioselective tandem cyclopropanation/Cope rearrangement of heteroaryldiazoacetates and their applications in natural product synthesis.
Olson, Jeremy Price.

Enantioselective tandem cyclopropanation/Cope rearrangement of heteroaryldiazoacetates and their applications in natural product synthesis. - 307 p.

Source: Dissertation Abstracts International, Volume: 70-09, Section: B, page: 5521.

Thesis (Ph.D.)--State University of New York at Buffalo, 2009.

The first section of this thesis focuses on the use of heteroaryldiazoacetates in the tandem cyclopropanation/Cope rearrangement. This reaction was found to be highly successful with various heteroaryldiazoacetates including the benzofuran, benzothiophene, and indolyl moieties. This methodology was applied to the formal synthesis of (+)-frondosin B, the total synthesis of (+)-frondosin B, and the total synthesis of epi-liphagal.

ISBN: 9781109343908Subjects--Topical Terms:

516206
Chemistry, Organic.

Enantioselective tandem cyclopropanation/Cope rearrangement of heteroaryldiazoacetates and their applications in natural product synthesis.
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020 $a 9781109343908
035 $a (UMI)AAI3372097
035 $a AAI3372097
040 $a UMI $c UMI
100 1 $a Olson, Jeremy Price. $3 1672654
245 1 0 $a Enantioselective tandem cyclopropanation/Cope rearrangement of heteroaryldiazoacetates and their applications in natural product synthesis.
300 $a 307 p.
500 $a Source: Dissertation Abstracts International, Volume: 70-09, Section: B, page: 5521.
500 $a Adviser: Huw M.L. Davies.
502 $a Thesis (Ph.D.)--State University of New York at Buffalo, 2009.
520 $a The first section of this thesis focuses on the use of heteroaryldiazoacetates in the tandem cyclopropanation/Cope rearrangement. This reaction was found to be highly successful with various heteroaryldiazoacetates including the benzofuran, benzothiophene, and indolyl moieties. This methodology was applied to the formal synthesis of (+)-frondosin B, the total synthesis of (+)-frondosin B, and the total synthesis of epi-liphagal.
520 $a The second section of this thesis focuses on the expansion of the Rhodium(II) catalyzed cyclopropanation into biological active compounds. These diaryl cyclopropylamines were found to have activity at both the dopamine and serotonin receptors, and are particularly of interest for there specicific 5-HT 2A receptor activity. In this section a series of 12 compounds were synthesized and tested for their biological activity at both the serotonin and dopamine receptors.
590 $a School code: 0656.
650 4 $a Chemistry, Organic. $3 516206
650 4 $a Chemistry, Pharmaceutical. $3 550957
690 $a 0490
690 $a 0491
710 2 $a State University of New York at Buffalo. $b Chemistry. $3 1035962
773 0 $t Dissertation Abstracts International $g 70-09B.
790 1 0 $a Davies, Huw M.L., $e advisor
790 1 0 $a Detty, Michael R. $e committee member
790 1 0 $a Hangauer, David G. $e committee member
790 1 0 $a Takeuchi, Kenneth J. $e committee member
790 $a 0656
791 $a Ph.D.
792 $a 2009
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3372097