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Molecular recognition induced small ...

Nakade, Hiroshi.

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Molecular recognition induced small molecule and polymer self-assembly .

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Molecular recognition induced small molecule and polymer self-assembly ./
作者:	Nakade, Hiroshi.
面頁冊數:	129 p.
附註:	Adviser: Vincent M. Rotello.
Contained By:	Dissertation Abstracts International68-03B.
標題:	Chemistry, Organic. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3254919

Molecular recognition induced small molecule and polymer self-assembly .
Nakade, Hiroshi.

Molecular recognition induced small molecule and polymer self-assembly . - 129 p.

Adviser: Vincent M. Rotello.

Thesis (Ph.D.)--University of Massachusetts Amherst, 2007.

Molecular self-assembly offers an effective approach to create highly ordered construct useful in materials science. We have demonstrated that molecular recognition dyads self-assemble into discrete helical structures via chiral translation, and the systems have exhibited liquid crystalline properties mediated by molecular recognition. Through combination of chiral translations, we have been able to highlight cooperative and frustrated self-assembled systems as a consequence of delicate interplay of chiralities. Small chirality changes in self-assembled systems are also essential in liquid crystalline properties to provide well-defined molecular organization. Imparting recognition elements with dendritic blocks enables control over self-assembled structures. In addition, we have demonstrated that complementary alternating copolymers self-assemble into ordered spherical aggregates through cooperative binding and duplex formation.Subjects--Topical Terms:

516206
Chemistry, Organic.

Molecular recognition induced small molecule and polymer self-assembly .
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245 1 0 $a Molecular recognition induced small molecule and polymer self-assembly .
300 $a 129 p.
500 $a Adviser: Vincent M. Rotello.
500 $a Source: Dissertation Abstracts International, Volume: 68-03, Section: B, page: 1644.
502 $a Thesis (Ph.D.)--University of Massachusetts Amherst, 2007.
520 $a Molecular self-assembly offers an effective approach to create highly ordered construct useful in materials science. We have demonstrated that molecular recognition dyads self-assemble into discrete helical structures via chiral translation, and the systems have exhibited liquid crystalline properties mediated by molecular recognition. Through combination of chiral translations, we have been able to highlight cooperative and frustrated self-assembled systems as a consequence of delicate interplay of chiralities. Small chirality changes in self-assembled systems are also essential in liquid crystalline properties to provide well-defined molecular organization. Imparting recognition elements with dendritic blocks enables control over self-assembled structures. In addition, we have demonstrated that complementary alternating copolymers self-assemble into ordered spherical aggregates through cooperative binding and duplex formation.
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650 4 $a Chemistry, Organic. $3 516206
650 4 $a Chemistry, Polymer. $3 1018428
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773 0 $t Dissertation Abstracts International $g 68-03B.
790 $a 0118
790 1 0 $a Rotello, Vincent M., $e advisor
791 $a Ph.D.
792 $a 2007
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3254919