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Homoleptic naked clusters of endohed...

Nalbant Esenturk, Emren.

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Homoleptic naked clusters of endohedral Zintl ions.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Homoleptic naked clusters of endohedral Zintl ions./
Author:	Nalbant Esenturk, Emren.
Description:	127 p.
Notes:	Adviser: Bryan W. Eichhorn.
Contained By:	Dissertation Abstracts International67-10B.
Subject:	Chemistry, Inorganic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3236723
ISBN:	9780542909986

Homoleptic naked clusters of endohedral Zintl ions.
Nalbant Esenturk, Emren.

Homoleptic naked clusters of endohedral Zintl ions. - 127 p.

Adviser: Bryan W. Eichhorn.

Thesis (Ph.D.)--University of Maryland, College Park, 2006.

Nanoclusters are of interest because of their remarkable catalytic properties and their application in nanotechnology fields. There is a strong preference toward bimetallic systems due to their superior catalytic properties compare to monometallic systems. Synthetic protocols are developed by using polyatomic main group clusters (Zintl ions) for making new bimetallic nano-catalysts. In this study, new, free standing, transition metal stabilized Zintl ions have been isolated. They are promising candidates to be used both in nanotechnology and heterogeneous catalysis.

ISBN: 9780542909986Subjects--Topical Terms:

517253
Chemistry, Inorganic.

Homoleptic naked clusters of endohedral Zintl ions.
LDR:03254nam 2200313 a 45 001 967238
005 20110915
008 110915s2006 eng d
020 $a 9780542909986
035 $a (UnM)AAI3236723
035 $a AAI3236723
040 $a UnM $c UnM
100 1 $a Nalbant Esenturk, Emren. $3 1291117
245 1 0 $a Homoleptic naked clusters of endohedral Zintl ions.
300 $a 127 p.
500 $a Adviser: Bryan W. Eichhorn.
500 $a Source: Dissertation Abstracts International, Volume: 67-10, Section: B, page: 5740.
502 $a Thesis (Ph.D.)--University of Maryland, College Park, 2006.
520 $a Nanoclusters are of interest because of their remarkable catalytic properties and their application in nanotechnology fields. There is a strong preference toward bimetallic systems due to their superior catalytic properties compare to monometallic systems. Synthetic protocols are developed by using polyatomic main group clusters (Zintl ions) for making new bimetallic nano-catalysts. In this study, new, free standing, transition metal stabilized Zintl ions have been isolated. They are promising candidates to be used both in nanotechnology and heterogeneous catalysis.
520 $a [M Pb12]2- (M = Ni, Pd, Pt) are the first isolated free-standing centered icosahedra without any attendant of ligands. The anions contain naked Pb12 icosahedra clusters encapsulating Group 10 transition metals and possess near perfect Ih point symmetry. These endohedral naked metal clusters have nontraditional spherical aromatic electronic structures. They are the smallest members of the nanoparticle growth sequence, M13 (centered icosahedra), with hcp lattices. Their positive chemical shifts in 207Pb NMR spectra contradict theoretical chemical shift calculations of isostructural aromatic clusters.
520 $a A new type of Zintl ion, [Ni Pb10]2-, has also been synthesized. The anion contains Ni atom centered in a closo-Pb 102- bicapped square antiprism, and possesses virtual D4d point symmetry. It is the first isolated ten atom, homoatomic naked Zintl ion cluster. The Pt and Pd analogs, and non-metallated Pb 10 and Pb12 clusters have also been observed in the gas phase by LDI-TOF-MS.
520 $a NMR spectroscopy was used to investigate unusual dynamic behaviors of the one focus [Ni Pb10]2- and two focus [Ni 2Sn17]4- anions and both demonstrated surprising global atomic mobility. The latter has a capsule like structure having central Sn atom with coordination number of eight. This extraordinary high coordination of the central Sn is more akin to solid state compounds.
520 $a The [Ge9Ni2(PPh3)]2- anion is the new example of Zintl ion, which do not adopt Wadian type structure. Another Ni-Ge system with exciting structure, [Ni6Ge13(CO) 5]4- is also isolated. The anion has interpenetrating biicosahedral structure which is unique to Zintl ion chemistry. The potential interconversion of [Ge9Ni2(PPh3)] 2- and [Ni6Ge13(CO)5]4- have been investigated through ESI-MS studies.
590 $a School code: 0117.
650 4 $a Chemistry, Inorganic. $3 517253
690 $a 0488
710 2 0 $a University of Maryland, College Park. $3 657686
773 0 $t Dissertation Abstracts International $g 67-10B.
790 $a 0117
790 1 0 $a Eichhorn, Bryan W., $e advisor
791 $a Ph.D.
792 $a 2006
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3236723