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Carbon nanotubes and nanocomposites ...
~
Wang, Wei.
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Carbon nanotubes and nanocomposites for thermal and electrical applications.
紀錄類型:
書目-語言資料,印刷品 : Monograph/item
正題名/作者:
Carbon nanotubes and nanocomposites for thermal and electrical applications./
作者:
Wang, Wei.
面頁冊數:
231 p.
附註:
Adviser: Ya-Ping Sun.
Contained By:
Dissertation Abstracts International69-03B.
標題:
Chemistry, Polymer. -
電子資源:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3304046
ISBN:
9780549519522
Carbon nanotubes and nanocomposites for thermal and electrical applications.
Wang, Wei.
Carbon nanotubes and nanocomposites for thermal and electrical applications.
- 231 p.
Adviser: Ya-Ping Sun.
Thesis (Ph.D.)--Clemson University, 2008.
The known electrical and thermal properties of carbon nanotubes have prompted many predictions on their extraordinary potentials for ultimately performing polymeric nanocomposites. In this dissertation, chemical modification and functionalization of carbon nanotubes have been demonstrated as being effective for high-quality polymeric carbon nanotube composites, especially with our approach of using polymers that are structurally identical or maximally similar to the matrix polymers in the nanotube functionalization. For example, a poly(N-vinyl carbazole) (PVK) copolymer containing pendant hydroxyl groups was synthesized for the functionalization of single-walled carbon nanotubes (SWNTs). The shared solubility of the functionalized nanotube samples with PVK matrix polymer enabled the wet-casting of high-quality PVK-SWNT nanocomposite thin films for an evaluation of their enhanced charge dissipation under photo illumination.
ISBN: 9780549519522Subjects--Topical Terms:
1018428
Chemistry, Polymer.
Carbon nanotubes and nanocomposites for thermal and electrical applications.
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The known electrical and thermal properties of carbon nanotubes have prompted many predictions on their extraordinary potentials for ultimately performing polymeric nanocomposites. In this dissertation, chemical modification and functionalization of carbon nanotubes have been demonstrated as being effective for high-quality polymeric carbon nanotube composites, especially with our approach of using polymers that are structurally identical or maximally similar to the matrix polymers in the nanotube functionalization. For example, a poly(N-vinyl carbazole) (PVK) copolymer containing pendant hydroxyl groups was synthesized for the functionalization of single-walled carbon nanotubes (SWNTs). The shared solubility of the functionalized nanotube samples with PVK matrix polymer enabled the wet-casting of high-quality PVK-SWNT nanocomposite thin films for an evaluation of their enhanced charge dissipation under photo illumination.
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For desired electrical properties, not only the dispersion of carbon nanotubes in the polymer matrix is important to the performance, but also the use of only metallic nanotubes may offer solutions in some of the more demanding applications. Here demonstrated is that the bulk-separated metallic SWNTs offer superior performance (consistently and substantially better than the as-produced nanotube sample) not only in conductive composites with both poly(3-hexylthiophene) and PEDOT:PSS matrixes, but also in transparent conductive coatings of neat SWNTs.
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