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Phenol removal from saturated porous...

Kim, Wongee.

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Phenol removal from saturated porous media using horseradish peroxidase mediated oxidative polymerization process.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Phenol removal from saturated porous media using horseradish peroxidase mediated oxidative polymerization process./
Author:	Kim, Wongee.
Description:	280 p.
Notes:	Adviser: Alok Bhandari.
Contained By:	Dissertation Abstracts International68-07B.
Subject:	Engineering, Environmental. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3274530
ISBN:	9780549126157

Phenol removal from saturated porous media using horseradish peroxidase mediated oxidative polymerization process.
Kim, Wongee.

Phenol removal from saturated porous media using horseradish peroxidase mediated oxidative polymerization process. - 280 p.

Adviser: Alok Bhandari.

Thesis (Ph.D.)--Kansas State University, 2007.

Aquifers are frequently contaminated by phenolic compounds from spills, leaking underground storage tanks, or landfills. These compounds can be toxic to a variety of organisms including humans. Their disposal is restricted in many countries with strict limits for acceptable concentrations in drinking water. Phenols that are chlorinated have significantly greater toxicity and are resistant to aerobic biodegradation. Enzyme-mediated in situ stabilization has been advocated as an approach for the treatment of phenolic compounds in soils and groundwater. This research investigated the applicability of a luminol-based chemiluminescence assay to monitor transport of horseradish peroxidase (HRP) enzyme in saturated porous media. The chemiluminescence assay was optimized by varying solution conditions such as the concentration of luminol, p-iodophenol, hydrogen peroxide, ionic strength and pH. All assay components were found to affect the maximum chemiluminescene intensity. The study also evaluated the ability of HRP to mediate the removal of phenol from solution by catalyzing its oxidative polymerization in simulated aquifer conditions. HRP behaved as a conservative tracer in the column packed with Ottawa sand. The concentration of phenol in the column effluent was found to decrease by nearly 90% in a presence of HRP and H2O2 in the continuous flow system. HRP-mediated oxidative polymerization of phenols resulted in the production of soluble and insoluble oligomeric products. Modification of porous media caused by the deposition of phenol polymerization products was studied and the impact of media modification on subsequent transport of phenolic contaminants was evaluated using 2,4-dichlorophenol (2,4-DCP) as a probe solute. The pore volume of the porous media was reduced due to the deposition of insoluble phenolic oligomers. The transport behavior of 2,4-DCP showed that the contaminant was retarded in the modified porous media.

ISBN: 9780549126157Subjects--Topical Terms:

783782
Engineering, Environmental.

Phenol removal from saturated porous media using horseradish peroxidase mediated oxidative polymerization process.
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020 $a 9780549126157
035 $a (UMI)AAI3274530
035 $a AAI3274530
040 $a UMI $c UMI
100 1 $a Kim, Wongee. $3 1272566
245 1 0 $a Phenol removal from saturated porous media using horseradish peroxidase mediated oxidative polymerization process.
300 $a 280 p.
500 $a Adviser: Alok Bhandari.
500 $a Source: Dissertation Abstracts International, Volume: 68-07, Section: B, page: 4745.
502 $a Thesis (Ph.D.)--Kansas State University, 2007.
520 $a Aquifers are frequently contaminated by phenolic compounds from spills, leaking underground storage tanks, or landfills. These compounds can be toxic to a variety of organisms including humans. Their disposal is restricted in many countries with strict limits for acceptable concentrations in drinking water. Phenols that are chlorinated have significantly greater toxicity and are resistant to aerobic biodegradation. Enzyme-mediated in situ stabilization has been advocated as an approach for the treatment of phenolic compounds in soils and groundwater. This research investigated the applicability of a luminol-based chemiluminescence assay to monitor transport of horseradish peroxidase (HRP) enzyme in saturated porous media. The chemiluminescence assay was optimized by varying solution conditions such as the concentration of luminol, p-iodophenol, hydrogen peroxide, ionic strength and pH. All assay components were found to affect the maximum chemiluminescene intensity. The study also evaluated the ability of HRP to mediate the removal of phenol from solution by catalyzing its oxidative polymerization in simulated aquifer conditions. HRP behaved as a conservative tracer in the column packed with Ottawa sand. The concentration of phenol in the column effluent was found to decrease by nearly 90% in a presence of HRP and H2O2 in the continuous flow system. HRP-mediated oxidative polymerization of phenols resulted in the production of soluble and insoluble oligomeric products. Modification of porous media caused by the deposition of phenol polymerization products was studied and the impact of media modification on subsequent transport of phenolic contaminants was evaluated using 2,4-dichlorophenol (2,4-DCP) as a probe solute. The pore volume of the porous media was reduced due to the deposition of insoluble phenolic oligomers. The transport behavior of 2,4-DCP showed that the contaminant was retarded in the modified porous media.
590 $a School code: 0100.
650 4 $a Engineering, Environmental. $3 783782
650 4 $a Engineering, Sanitary and Municipal. $3 1018731
650 4 $a Environmental Sciences. $3 676987
690 $a 0554
690 $a 0768
690 $a 0775
710 2 $a Kansas State University. $b Department of Civil Engineering. $3 1272567
773 0 $t Dissertation Abstracts International $g 68-07B.
790 $a 0100
790 1 0 $a Bhandari, Alok $e committee member
790 1 0 $a Bhandari, Alok, $e advisor
790 1 0 $a Hohn, Keith $e committee member
790 1 0 $a Klabunde, Kenneth J. $e committee member
790 1 0 $a Kluitenberg, Gerard $e committee member
790 1 0 $a Reddi, Lakshmi N. $e committee member
791 $a Ph.D.
792 $a 2007
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3274530