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Assessment of biogeochemical deposit...

Mulla Saleh, Abdul R.

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Assessment of biogeochemical deposits in landfill leachate drainage systems: Phase II.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Assessment of biogeochemical deposits in landfill leachate drainage systems: Phase II./
Author:	Mulla Saleh, Abdul R.
Description:	305 p.
Notes:	Advisers: Robert Carnahan; Jerry Murphy.
Contained By:	Dissertation Abstracts International68-01B.
Subject:	Biogeochemistry. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3248296

Assessment of biogeochemical deposits in landfill leachate drainage systems: Phase II.
Mulla Saleh, Abdul R.

Assessment of biogeochemical deposits in landfill leachate drainage systems: Phase II. - 305 p.

Advisers: Robert Carnahan; Jerry Murphy.

Thesis (Ph.D.)--University of South Florida, 2006.

Land disposal of solid waste is a vital component of any solid waste management system. Design, operation and closure of municipal solid waste (MSW) landfills are required by regulations to control leachate and gases generated during the life, closure, and post-closure of the facility. Clogging of leachate drainage and removal systems in landfills is a common phenomenon and has been acknowledged in several landfills throughout the United States and abroad.Subjects--Topical Terms:

545717
Biogeochemistry.

Assessment of biogeochemical deposits in landfill leachate drainage systems: Phase II.
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035 $a (UMI)AAI3248296
035 $a AAI3248296
040 $a UMI $c UMI
100 1 $a Mulla Saleh, Abdul R. $3 1269292
245 1 0 $a Assessment of biogeochemical deposits in landfill leachate drainage systems: Phase II.
300 $a 305 p.
500 $a Advisers: Robert Carnahan; Jerry Murphy.
500 $a Source: Dissertation Abstracts International, Volume: 68-01, Section: B, page: 0541.
502 $a Thesis (Ph.D.)--University of South Florida, 2006.
520 $a Land disposal of solid waste is a vital component of any solid waste management system. Design, operation and closure of municipal solid waste (MSW) landfills are required by regulations to control leachate and gases generated during the life, closure, and post-closure of the facility. Clogging of leachate drainage and removal systems in landfills is a common phenomenon and has been acknowledged in several landfills throughout the United States and abroad.
520 $a This project was conducted in two phases. Phase I was completed in February of 2005 and Phase II was completed in August of 2006. Leachate characteristics data obtained in Phase I was processed and analyzed, along with supplementary data obtained in Phase II on liquid and solid phase testing. Leachate samples from the landfill and lysimeters indicated the presence of iron and sulfate-reducing bacteria. These bacteria are known to facilitate biologically induced precipitate formation.
520 $a The mechanism by which biologically induced precipitate may form begins with oxidizing acetate by iron and sulfate-reducing bacteria, reducing sulfate to sulfide and ferric iron to ferrous, and then forming calcium carbonate, iron sulfate, and possibly dolomite and other minerals.
520 $a The results show that the clogging mechanism is driven by two major processes: transformation of volatile acids to substrates by iron and sulfate-reducing bacteria causing local pH and total carbonate to increase, which accelerate calcium carbonate precipitation, and thermodynamically favored reactions in supersaturated conditions based on saturation indices of calcium, sulfide, iron, and other species with respect to minerals. For each 1 mg of consumed volatile acids there were 1.7 mg of calcium, 0.28 mg of sulfate, and 0.03 mg of iron removed.
520 $a Field and lysimeter precipitate samples were analyzed (using X-Ray Diffraction, Scanning Electron microscopy, and Electron Dispersive Spectroscopy) and correlated with geochemical modeling of leachate constituents. Precipitate analyses showed the presence of calcium carbonate, brushite (calcium phosphate), and dolomite, where as geochemical modeling showed that calcium carbonate, hydroxyapatite (complex of calcium phosphate), dolomite, pyrite, and siderite may be formed from field and lysimeter leachate constituents. The results also showed that submerged and stagnant conditions in the leachate collection systems accelerate the precipitation process.
590 $a School code: 0206.
650 4 $a Biogeochemistry. $3 545717
650 4 $a Biology, Microbiology. $3 1017734
650 4 $a Engineering, Civil. $3 783781
650 4 $a Engineering, Environmental. $3 783782
650 4 $a Geochemistry. $3 539092
690 $a 0410
690 $a 0425
690 $a 0543
690 $a 0775
690 $a 0996
710 2 $a University of South Florida. $3 1020446
773 0 $t Dissertation Abstracts International $g 68-01B.
790 $a 0206
790 1 0 $a Carnahan, Robert, $e advisor
790 1 0 $a Murphy, Jerry, $e advisor
791 $a Ph.D.
792 $a 2006
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3248296