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Design, synthesis, and supramolecula...

Wang, Hui.

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Design, synthesis, and supramolecular surface chemistry of bi- and tridentate surface anchors for nanoscience and nanobiotechnology.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Design, synthesis, and supramolecular surface chemistry of bi- and tridentate surface anchors for nanoscience and nanobiotechnology./
Author:	Wang, Hui.
Description:	155 p.
Notes:	Adviser: Jun Hu.
Contained By:	Dissertation Abstracts International68-09B.
Subject:	Chemistry, Inorganic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3280841
ISBN:	9780549225133

Design, synthesis, and supramolecular surface chemistry of bi- and tridentate surface anchors for nanoscience and nanobiotechnology.
Wang, Hui.

Design, synthesis, and supramolecular surface chemistry of bi- and tridentate surface anchors for nanoscience and nanobiotechnology. - 155 p.

Adviser: Jun Hu.

Thesis (Ph.D.)--The University of Akron, 2007.

This dissertation describes the design, synthesis, and supramolecular surface chemistry of bi- and tri-dentate surface anchors for nanoscience and nanobiotechnology. Molecular electronic device candidates, based on the tridentate surface anchor 2,4,9-trithia-tricyclo[3.3.1.13,7]decane, were used to bridge two ruthenium metal clusters. These well-designed ruthenium complexes were used as nanometer-sized molecular connector/metal cluster models to investigate the surface binding characteristics of tridentate surface anchor-metal junctions.

ISBN: 9780549225133Subjects--Topical Terms:

517253
Chemistry, Inorganic.

Design, synthesis, and supramolecular surface chemistry of bi- and tridentate surface anchors for nanoscience and nanobiotechnology.
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005 20110518
008 110518s2007 ||||||||||||||||| ||eng d
020 $a 9780549225133
035 $a (UMI)AAI3280841
035 $a AAI3280841
040 $a UMI $c UMI
100 1 $a Wang, Hui. $3 836732
245 1 0 $a Design, synthesis, and supramolecular surface chemistry of bi- and tridentate surface anchors for nanoscience and nanobiotechnology.
300 $a 155 p.
500 $a Adviser: Jun Hu.
500 $a Source: Dissertation Abstracts International, Volume: 68-09, Section: B, page: 5952.
502 $a Thesis (Ph.D.)--The University of Akron, 2007.
520 $a This dissertation describes the design, synthesis, and supramolecular surface chemistry of bi- and tri-dentate surface anchors for nanoscience and nanobiotechnology. Molecular electronic device candidates, based on the tridentate surface anchor 2,4,9-trithia-tricyclo[3.3.1.13,7]decane, were used to bridge two ruthenium metal clusters. These well-designed ruthenium complexes were used as nanometer-sized molecular connector/metal cluster models to investigate the surface binding characteristics of tridentate surface anchor-metal junctions.
520 $a Bi-dentate surface anchors, 1,4-dimercapto-2,3-dimethyl-butane- 2,3-diol and 4,5-dimethyl-2-(4-vinyl-phenyl)-[1,3,2]dioxaborolane-4,5-dithiol, were synthesized. They were used as ligands for stabilizing gold nanoparticles by two methods: direct reduction reaction, and ligand exchange reaction with triphenylphosphine-stabilized gold nanoparticles. The orientation of the bi-dentate surface anchor-based self-assembled monolayers (SAMs) on the flat gold surface was studied by Polarization Modulation Fourier Transform Infrared Reflection Absorption Spectroscopy (PM-FTIRRAS), which showed freestanding surface binding capability of the bi-dentate surface anchors.
520 $a New methods to conjugate carbohydrates on the surfaces of gold nanoparticles by the tridentate surface anchor, 2,4,9-trithia-tricyclo[3.3.1.13,7 ]decane, were studied. Several derivatives of 7-substituted-2,4,9-trithia-tricyclo[3.3.1.1 3,7]decane were designed and synthesized for this purpose. Two different functional groups, methoxyamino group and terminal alkyne group, can be used to bind to reductive sugars and azido-sugars respectively. These compounds were used as ligands for stabilizing gold nanoparticles by ligand exchange reaction with triphenylphosphine-stabilized gold nanoparticles. The PM-FTIRRAS characterizations of the tri-dentate surface anchor SAM on flat gold surfaces were also studied.
590 $a School code: 0003.
650 4 $a Chemistry, Inorganic. $3 517253
650 4 $a Chemistry, Organic. $3 516206
690 $a 0488
690 $a 0490
710 2 $a The University of Akron. $3 1018399
773 0 $t Dissertation Abstracts International $g 68-09B.
790 $a 0003
790 1 0 $a Hu, Jun, $e advisor
791 $a Ph.D.
792 $a 2007
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3280841