東華大學圖書館 |

Language: English

Help

回圖書館首頁

手機版館藏查詢

Back

Switch To: Labeled | MARC Mode | ISBD

Rational synthesis of polar and chir...

Evans, Owen Richard.

Linked to FindBook

Google Book

Amazon

博客來

Rational synthesis of polar and chiral solids for applications in nonlinear optics, asymmetric catalysis and chiral separation.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Rational synthesis of polar and chiral solids for applications in nonlinear optics, asymmetric catalysis and chiral separation./
Author:	Evans, Owen Richard.
Description:	194 p.
Notes:	Adviser: Wenbin Lin.
Contained By:	Dissertation Abstracts International62-12B.
Subject:	Chemistry, Inorganic. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3036415
ISBN:	0493492496

Rational synthesis of polar and chiral solids for applications in nonlinear optics, asymmetric catalysis and chiral separation.
Evans, Owen Richard.

Rational synthesis of polar and chiral solids for applications in nonlinear optics, asymmetric catalysis and chiral separation. - 194 p.

Adviser: Wenbin Lin.

Thesis (Ph.D.)--Brandeis University, 2002.

Despite the great progress made in the synthesis of organic nonlinear optical (NLO) materials over the past two decades, two key issues remain and thus far prevent their practical applications. First, organizing organic chromophores into an acentric bulk is still a daunting task. Second, the tradeoff between optical nonlinearity and transparency has yet to be improved. Part one of this thesis will detail a research program on the crystal engineering of acentric coordination networks for second-order NLO applications. We have devised two general approaches based on metal-coordination directed self-assembly processes for the preparation of acentric coordination networks: interpenetrated diamondoid networks and 2-D square grids. These coordination networks are intrinsically acentric and have an improved optical nonlinearity-transparency tradeoff. Detailed synthetic strategies and second-order NLO properties of these novel polymeric materials will be described.

ISBN: 0493492496Subjects--Topical Terms:

517253
Chemistry, Inorganic.

Rational synthesis of polar and chiral solids for applications in nonlinear optics, asymmetric catalysis and chiral separation.
LDR:02520nam 2200277 a 45 001 937812
005 20110511
008 110511s2002 eng d
020 $a 0493492496
035 $a (UnM)AAI3036415
035 $a AAI3036415
040 $a UnM $c UnM
100 1 $a Evans, Owen Richard. $3 1261668
245 1 0 $a Rational synthesis of polar and chiral solids for applications in nonlinear optics, asymmetric catalysis and chiral separation.
300 $a 194 p.
500 $a Adviser: Wenbin Lin.
500 $a Source: Dissertation Abstracts International, Volume: 62-12, Section: B, page: 5720.
502 $a Thesis (Ph.D.)--Brandeis University, 2002.
520 $a Despite the great progress made in the synthesis of organic nonlinear optical (NLO) materials over the past two decades, two key issues remain and thus far prevent their practical applications. First, organizing organic chromophores into an acentric bulk is still a daunting task. Second, the tradeoff between optical nonlinearity and transparency has yet to be improved. Part one of this thesis will detail a research program on the crystal engineering of acentric coordination networks for second-order NLO applications. We have devised two general approaches based on metal-coordination directed self-assembly processes for the preparation of acentric coordination networks: interpenetrated diamondoid networks and 2-D square grids. These coordination networks are intrinsically acentric and have an improved optical nonlinearity-transparency tradeoff. Detailed synthetic strategies and second-order NLO properties of these novel polymeric materials will be described.
520 $a The past few years has witnessed tremendous progress in the design and synthesis of functional metal-organic frameworks. In particular robust porous coordination networks capable of functional group and size-selective sorption have recently been synthesized. Despite this tremendous progress, the use of homochiral metal-organic frameworks in heterogeneous asymmetric catalysis and enantioselective separation has not been extensively explored. Part two of this thesis will detail research towards the design and synthesis of homochiral porous metal-organic frameworks capable of heterogeneous asymmetric catalysis and chiral separation.
590 $a School code: 0021.
650 4 $a Chemistry, Inorganic. $3 517253
690 $a 0488
710 2 0 $a Brandeis University. $3 1017415
773 0 $t Dissertation Abstracts International $g 62-12B.
790 $a 0021
790 1 0 $a Lin, Wenbin, $e advisor
791 $a Ph.D.
792 $a 2002
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3036415