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Trace element solubility from land a...

Jackson, Brian Philip.

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Trace element solubility from land application of fly ash/organic waste mixtures with emphasis on arsenic and selenium speciation.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	Trace element solubility from land application of fly ash/organic waste mixtures with emphasis on arsenic and selenium speciation./
Author:	Jackson, Brian Philip.
Description:	151 p.
Notes:	Director: William P. Miller.
Contained By:	Dissertation Abstracts International59-04B.
Subject:	Agriculture, Agronomy. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=9828383
ISBN:	0591809435

Trace element solubility from land application of fly ash/organic waste mixtures with emphasis on arsenic and selenium speciation.
Jackson, Brian Philip.

Trace element solubility from land application of fly ash/organic waste mixtures with emphasis on arsenic and selenium speciation. - 151 p.

Director: William P. Miller.

Thesis (Ph.D.)--University of Georgia, 1998.

Mixing of coal fly ash with organic wastes to provide balanced soil amendments offers a potential viable utilization of this industrial by-product; however, trace element solubility needs to be evaluated. Soil solution speciation of As and Se from fly ash/organic waste mixtures is also of environmental concern. Coupling of ion chromatography with inductively coupled plasma mass spectrometry (IC-ICP-MS) has proved an effective method for determining As speciation at trace concentrations; however, ICP-MS has not previously been used for multi-element detection in As and Se speciation analysis. Two fly ashes mixed with either poultry litter or sewage sludge at ratios of 4:l and 2:1, respectively, were land-applied to a Cecil sandy loam at application rates of 80 Mg ha$\sp{-1}$ fly ash, 20 Mg ha$\sp{-1}$ poultry litter, and 40 Mg ha$\sp{-1}$ sewage sludge. Maize was planted on the amended field plots and tension lysimeters were used to collect soil solution. Increased soluble concentrations of P, C, Cu, As, Se, Mo, and Cr were determined in fly ash/poultry litter plots relative to fly ash/sewage sludge plots: Increased soluble P and organic C from the poultry litter may have increased soluble oxyanion concentrations from the fly ash. Increased soil solution concentrations were transient, decreasing to near control levels after approximately 30 days. A subsequent laboratory incubation study indicated that Cu was highly soluble from poultry litter, and that soluble Cu was highly correlated with soluble C. The poultry litter was also a significant source of soluble As. Mixing of fly ash with either organic waste increased soluble Se concentrations relative to land application of the fly ash alone. Soil solution speciation showed that Se was present as selenate, Se(VI), and increased soluble Se may have resulted from higher pH and increased sulfate concentrations of the fly ash/organic waste mixtures. Soluble As was present as As(V) in fly ash-amended soils, while dimethylarsinate (DMA) was the predominate species in fly ash/poultry litter-amended soils. IC-ICP-MS proved an effective technique for As and Se speciation analysis in environmental samples, yielding detection limits of $<

ISBN: 0591809435Subjects--Topical Terms:

1018679
Agriculture, Agronomy.

Trace element solubility from land application of fly ash/organic waste mixtures with emphasis on arsenic and selenium speciation.
LDR:03236nam 2200301 a 45 001 933168
005 20110505
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020 $a 0591809435
035 $a (UnM)AAI9828383
035 $a AAI9828383
040 $a UnM $c UnM
100 1 $a Jackson, Brian Philip. $3 1256907
245 1 0 $a Trace element solubility from land application of fly ash/organic waste mixtures with emphasis on arsenic and selenium speciation.
300 $a 151 p.
500 $a Director: William P. Miller.
500 $a Source: Dissertation Abstracts International, Volume: 59-04, Section: B, page: 1545.
502 $a Thesis (Ph.D.)--University of Georgia, 1998.
520 $a Mixing of coal fly ash with organic wastes to provide balanced soil amendments offers a potential viable utilization of this industrial by-product; however, trace element solubility needs to be evaluated. Soil solution speciation of As and Se from fly ash/organic waste mixtures is also of environmental concern. Coupling of ion chromatography with inductively coupled plasma mass spectrometry (IC-ICP-MS) has proved an effective method for determining As speciation at trace concentrations; however, ICP-MS has not previously been used for multi-element detection in As and Se speciation analysis. Two fly ashes mixed with either poultry litter or sewage sludge at ratios of 4:l and 2:1, respectively, were land-applied to a Cecil sandy loam at application rates of 80 Mg ha$\sp{-1}$ fly ash, 20 Mg ha$\sp{-1}$ poultry litter, and 40 Mg ha$\sp{-1}$ sewage sludge. Maize was planted on the amended field plots and tension lysimeters were used to collect soil solution. Increased soluble concentrations of P, C, Cu, As, Se, Mo, and Cr were determined in fly ash/poultry litter plots relative to fly ash/sewage sludge plots: Increased soluble P and organic C from the poultry litter may have increased soluble oxyanion concentrations from the fly ash. Increased soil solution concentrations were transient, decreasing to near control levels after approximately 30 days. A subsequent laboratory incubation study indicated that Cu was highly soluble from poultry litter, and that soluble Cu was highly correlated with soluble C. The poultry litter was also a significant source of soluble As. Mixing of fly ash with either organic waste increased soluble Se concentrations relative to land application of the fly ash alone. Soil solution speciation showed that Se was present as selenate, Se(VI), and increased soluble Se may have resulted from higher pH and increased sulfate concentrations of the fly ash/organic waste mixtures. Soluble As was present as As(V) in fly ash-amended soils, while dimethylarsinate (DMA) was the predominate species in fly ash/poultry litter-amended soils. IC-ICP-MS proved an effective technique for As and Se speciation analysis in environmental samples, yielding detection limits of $< $1 $\mu $g L$\sp{-1}$ for all species analyzed.
590 $a School code: 0077.
650 4 $a Agriculture, Agronomy. $3 1018679
650 4 $a Agriculture, Soil Science. $3 1017824
650 4 $a Environmental Sciences. $3 676987
650 4 $a Geochemistry. $3 539092
690 $a 0285
690 $a 0481
690 $a 0768
690 $a 0996
710 2 0 $a University of Georgia. $3 515076
773 0 $t Dissertation Abstracts International $g 59-04B.
790 $a 0077
790 1 0 $a Miller, William P., $e advisor
791 $a Ph.D.
792 $a 1998
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=9828383