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Ozonation of Canadian Athabasca asph...

The University of Utah.

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Ozonation of Canadian Athabasca asphaltene.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Ozonation of Canadian Athabasca asphaltene./
Author:	Cha, Zhixiong.
Description:	186 p.
Notes:	Source: Dissertation Abstracts International, Volume: 70-03, Section: B, page: 1800.
Contained By:	Dissertation Abstracts International70-03B.
Subject:	Energy. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3349468
ISBN:	9781109055559

Ozonation of Canadian Athabasca asphaltene.
Cha, Zhixiong.

Ozonation of Canadian Athabasca asphaltene. - 186 p.

Source: Dissertation Abstracts International, Volume: 70-03, Section: B, page: 1800.

Thesis (Ph.D.)--The University of Utah, 2009.

Application of ozonation in the petrochemical industry for heavy hydrocarbon upgrading has not been sufficiently explored. Among heavy hydrocarbons, asphaltenes are the heaviest and the most difficult fractions for analysis and treatment. Therefore, ozonation of asphaltenes presents an interesting application in the petrochemical industry.

ISBN: 9781109055559Subjects--Topical Terms:

876794
Energy.

Ozonation of Canadian Athabasca asphaltene.
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100 1 $a Cha, Zhixiong. $3 1058383
245 1 0 $a Ozonation of Canadian Athabasca asphaltene.
300 $a 186 p.
500 $a Source: Dissertation Abstracts International, Volume: 70-03, Section: B, page: 1800.
502 $a Thesis (Ph.D.)--The University of Utah, 2009.
520 $a Application of ozonation in the petrochemical industry for heavy hydrocarbon upgrading has not been sufficiently explored. Among heavy hydrocarbons, asphaltenes are the heaviest and the most difficult fractions for analysis and treatment. Therefore, ozonation of asphaltenes presents an interesting application in the petrochemical industry.
520 $a Commercial application of ozonation in the petrochemical industry has three obstacles: availability of an ozone-resistant and environmentally friendly solvent, the precipitation of ozonation intermediates during reaction, and recovery of the solvent and separation of the ozonation products. Preliminary ozonation of Athabasca oil sands asphaltene in nonparticipating solvents encountered serious precipitation of the ozonation intermediates. The precipitated intermediates could be polymeric ozonides and intermolecular ozonides or polymeric peroxides. Because the inhomogeneous reaction medium caused low ozone efficiency, various participating solvents such as methanol and acetic acid were added to form more soluble hydroperoxides. The mass balance results showed that on average, one asphaltene molecule reacted with 12 ozone molecules through the electrophilic reaction and the subsequent decomposition of ozonation intermediates generated acetone extractable products. GC/MS analysis of these compounds indicated that the free radical reactions could be important for generation of volatile products. The extensively ozonated asphaltene in the presence of participating solvents were refluxed with methanol to generate more volatile products. GC/MS analysis of the methanol-esterified ozonation products indicated that most volatile products were aliphatic carboxylic acid esters generated through cleavage of substituents. Reaction kinetics study showed that asphaltene ozonation was initially a diffusion rate-controlled reaction and later developed to a chemical reaction rate-controlled reaction after depletion of the reactive aromatic sites. Two new solvent systems, a self-sustaining ozonation system and a cyclohexane/acetone/water or a cyclohexane/acetone/methanol system, were studied to overcome the drawback of using halogenated solvents. The self-sustaining ozonation process employed the final ozonation products as the reaction solvent. Compared to the self-sustaining ozonation, the cyclohexane solvent system showed higher ozone efficiency; however, it required dynamic adjustment of the solvent system during ozonation.
520 $a An extensively ozonated asphaltene's weight would be doubled. Distillation of the products separated about 45% volatile products having biodiesel-style chemical structures. Compared to distillation, more than 90% of the ozonation products were extractable by acetone. The remaining acetone-insoluble part was further classified by dichloromethane and other solvents of different polarities. The separated ozonation products were good fuel additives or materials for other products.
590 $a School code: 0240.
650 4 $a Energy. $3 876794
650 4 $a Engineering, Chemical. $3 1018531
650 4 $a Engineering, Environmental. $3 783782
650 4 $a Engineering, Petroleum. $3 1018448
690 $a 0542
690 $a 0765
690 $a 0775
690 $a 0791
710 2 $a The University of Utah. $3 1017410
773 0 $t Dissertation Abstracts International $g 70-03B.
790 $a 0240
791 $a Ph.D.
792 $a 2009
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3349468