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Ionic liquids: Syntheses, characteri...

The University of Texas at Arlington., Chemistry & Biochemistry.

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Ionic liquids: Syntheses, characterization and applications in analytical chemistry.

紀錄類型:	書目-電子資源 : Monograph/item
正題名/作者:	Ionic liquids: Syntheses, characterization and applications in analytical chemistry./
作者:	Sharma, Pritesh S.
面頁冊數:	107 p.
附註:	Adviser: Daniel W. Armstrong.
Contained By:	Masters Abstracts International46-06.
標題:	Chemistry, Analytical. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=1453427
ISBN:	9780549560401

Ionic liquids: Syntheses, characterization and applications in analytical chemistry.
Sharma, Pritesh S.

Ionic liquids: Syntheses, characterization and applications in analytical chemistry. - 107 p.

Adviser: Daniel W. Armstrong.

Thesis (M.S.)--The University of Texas at Arlington, 2008.

Multifunctional ionic liquids (esp. dicationic and dianionic) have been shown to have a greater range of physical properties than most traditional, singly charged ILs. In this work, 28 novel tricationic ILs with specific structural variations have been synthesized in order to investigate the effect on their physicochemical properties. It was observed that the physicochemical properties can be varied to a greater extent in tricationic ILs than in traditional ILs. The central core of the tricationic IL itself can have different degrees of flexibility and these moieties can be altered as can the charge carrying groups to produce ILs with the desired physicochemical properties. These ILs have a greater range of viscosities and higher thermal stabilities than typical imidazolium based singly charged ionic liquids. Anion effects are also prominent with these highly tunable ionic liquids.

ISBN: 9780549560401Subjects--Topical Terms:

586156
Chemistry, Analytical.

Ionic liquids: Syntheses, characterization and applications in analytical chemistry.
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502 $a Thesis (M.S.)--The University of Texas at Arlington, 2008.
520 $a Multifunctional ionic liquids (esp. dicationic and dianionic) have been shown to have a greater range of physical properties than most traditional, singly charged ILs. In this work, 28 novel tricationic ILs with specific structural variations have been synthesized in order to investigate the effect on their physicochemical properties. It was observed that the physicochemical properties can be varied to a greater extent in tricationic ILs than in traditional ILs. The central core of the tricationic IL itself can have different degrees of flexibility and these moieties can be altered as can the charge carrying groups to produce ILs with the desired physicochemical properties. These ILs have a greater range of viscosities and higher thermal stabilities than typical imidazolium based singly charged ionic liquids. Anion effects are also prominent with these highly tunable ionic liquids.
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