東華大學圖書館 |

語系: 繁體中文

說明(常見問題)

回圖書館首頁

手機版館藏查詢

登入

回首頁

切換: 標籤 | MARC模式 | ISBD

Polymer side-chains as arms for mole...

Georgia Institute of Technology.

FindBook

Google Book

Amazon

博客來

Polymer side-chains as arms for molecular recognition.

紀錄類型:	書目-語言資料,印刷品 : Monograph/item
正題名/作者:	Polymer side-chains as arms for molecular recognition./
作者:	South, Clinton Ray.
面頁冊數:	361 p.
附註:	Adviser: Marcus Weck.
Contained By:	Dissertation Abstracts International69-04B.
標題:	Chemistry, Organic. -
電子資源:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3308831
ISBN:	9780549569640

Polymer side-chains as arms for molecular recognition.
South, Clinton Ray.

Polymer side-chains as arms for molecular recognition. - 361 p.

Adviser: Marcus Weck.

Thesis (Ph.D.)--Georgia Institute of Technology, 2008.

Finally, Chapter 9 summarizes the main conclusions of each chapter and presents a potential view of new projects that might result from the research presented in this thesis.

ISBN: 9780549569640Subjects--Topical Terms:

516206
Chemistry, Organic.

Polymer side-chains as arms for molecular recognition.
LDR:03596nam 2200349 a 45 001 856744
005 20100709
008 100709s2008 ||||||||||||||||| ||eng d
020 $a 9780549569640
035 $a (UMI)AAI3308831
035 $a AAI3308831
040 $a UMI $c UMI
100 1 $a South, Clinton Ray. $3 1023603
245 1 0 $a Polymer side-chains as arms for molecular recognition.
300 $a 361 p.
500 $a Adviser: Marcus Weck.
500 $a Source: Dissertation Abstracts International, Volume: 69-04, Section: B, page: 2350.
502 $a Thesis (Ph.D.)--Georgia Institute of Technology, 2008.
520 $a Finally, Chapter 9 summarizes the main conclusions of each chapter and presents a potential view of new projects that might result from the research presented in this thesis.
520 $a This thesis describes research based on synthetic protocols, methodologies, and applications of polymers containing side-chain molecular recognition elements. The motivation for the thesis lies in the belief among many in the field that a strict covalent paradigm for polymer chemistry is reaching its limit. The use of molecular recognition, in lieu of covalent chemistry, potentially presents a path through the current limits of polymer science. The work described in the following chapters of this thesis is, at least in part, a testament to this proposal.
520 $a The first two chapters present a basic introduction and survey of the fundamental noncovalent interactions that are ubiquitous in the research of supramolecular polymers and molecular recognition. A hierarchy of noncovalent interactions, molecular recognition, and self-assembly is outlined and discussed. Chapter 2 lays the foundation for the remaining chapters of this thesis by presenting several examples of prior work related specifically to the use of molecular recognition on the side-chains of polymers.
520 $a The next two chapters present research focused on advancing the functionalization of polymers through molecular recognition. The goal of this research is primarily to develop a general polymer backbone that both site-specifically and strongly associates noncovalently with small molecular substrates. These chapters demonstrate that both architecturally controlled block copolymers and random terpolymers can accept a full load of different substrates without interference among distinct molecular recognition elements along the polymer backbone.
520 $a Chapters 5 and 6 present a unique application of polymers containing molecular recognition elements, templated synthesis. Chapter 5 first discusses lessons learned from small molecule based templated synthesis in which a template and a substrate are held together by metal coordination and a subsequent bond forming reaction occurs. Ultimately, the results of this chapter directed our work towards a hydrogen bonding based system in lieu of metal coordination. In this case, a polymeric template was used, and a daughter monomer was polymerized while attached to the template.
520 $a Another application of polymers containing molecular recognition elements is presented in Chapters 7 and 8. In these chapters, metal coordination is used to assemble polymer multilayer thin films that are both responsive to external stimuli, stable, and erasable.
590 $a School code: 0078.
650 4 $a Chemistry, Organic. $3 516206
650 4 $a Chemistry, Polymer. $3 1018428
650 4 $a Engineering, Materials Science. $3 1017759
690 $a 0490
690 $a 0495
690 $a 0794
710 2 $a Georgia Institute of Technology. $3 696730
773 0 $t Dissertation Abstracts International $g 69-04B.
790 $a 0078
790 1 0 $a Weck, Marcus, $e advisor
791 $a Ph.D.
792 $a 2008
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3308831