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A study of the microstructure-proper...

Arizona State University.

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A study of the microstructure-property relationship for MFI-type zeolite membranes for xylene separation.

Record Type:	Language materials, printed : Monograph/item
Title/Author:	A study of the microstructure-property relationship for MFI-type zeolite membranes for xylene separation./
Author:	O'Brien, Jessica.
Description:	140 p.
Notes:	Source: Dissertation Abstracts International, Volume: 70-04, Section: B, page: 2435.
Contained By:	Dissertation Abstracts International70-04B.
Subject:	Engineering, Chemical. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3353882
ISBN:	9781109107555

A study of the microstructure-property relationship for MFI-type zeolite membranes for xylene separation.
O'Brien, Jessica.

A study of the microstructure-property relationship for MFI-type zeolite membranes for xylene separation. - 140 p.

Source: Dissertation Abstracts International, Volume: 70-04, Section: B, page: 2435.

Thesis (Ph.D.)--Arizona State University, 2009.

Observation of the differences in transport and separation capability through MFI membranes of varying microstructure and defect concentrations show these properties can significantly affect membrane performance as well as mechanical stability.

ISBN: 9781109107555Subjects--Topical Terms:

1018531
Engineering, Chemical.

A study of the microstructure-property relationship for MFI-type zeolite membranes for xylene separation.
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020 $a 9781109107555
035 $a (UMI)AAI3353882
035 $a AAI3353882
040 $a UMI $c UMI
100 1 $a O'Brien, Jessica. $3 1020773
245 1 2 $a A study of the microstructure-property relationship for MFI-type zeolite membranes for xylene separation.
300 $a 140 p.
500 $a Source: Dissertation Abstracts International, Volume: 70-04, Section: B, page: 2435.
502 $a Thesis (Ph.D.)--Arizona State University, 2009.
520 $a Observation of the differences in transport and separation capability through MFI membranes of varying microstructure and defect concentrations show these properties can significantly affect membrane performance as well as mechanical stability.
520 $a Effective separation of xylene isomers is possible through continuous membrane processes, specifically pervaporation, utilizing MFI-type zeolite membranes. The average pore size of MFI-type zeolite (0.6 nanometers) is large enough to allow para-xylene (molecular size &sim;0.56 nanometers) to pass and excludes bulkier ortho- and meta-isomers (molecular size &sim;0.68 nanometers). Separation through MFI-type zeolite occurs via transport differences of each isomer across the membrane and it is desired to exploit this property for use in pervaporation. Currently, MFI-type membranes have demonstrated the ability to separate xylene isomers under vapor permeation conditions where the partial pressures of xylene are extremely low resulting in impractically low flux values; at increased xylene exposure the separation capability is lost.
520 $a The objective of this dissertation is to present a fundamental study on the transport of xylene isomers through MFI-type zeolite membranes of varying microstructure in an effort address this problem. There are three fundamental areas which are covered: (1) the relationship between synthesis, microstructure, quality, and separation performance of xylene isomers, (2) determination of how the adsorption properties of the xylene-MFI system (specifically adsorbate-zeolite and adsorbate-adsorbate interactions) affect separation capability, and (3) how to tailor the MFI type zeolite membranes for optimum performance in terms of para-xylene selectivity, flux and stability when operating under pervaporation conditions.
520 $a Fundamental studies demonstrate that the framework distortion experienced by the MFI zeolite at high para-xylene loading results in the loss of molecular sieving capability and is the cause of poor pervaporation separation performance rather than the presence of intercrystalline defects. These findings shift the focus from development of a defect-free membrane to one with enhanced framework rigidity. Studies into isomorphous substitution of Si in the MFI framework and synthesis of bilayer structures direct the development of silicalite/ZSM-5 bilayer membranes which exhibit significantly enhanced para-xylene selectivity, reasonable flux, and performance stability under pervaporation conditions.
590 $a School code: 0010.
650 4 $a Engineering, Chemical. $3 1018531
650 4 $a Engineering, Materials Science. $3 1017759
650 4 $a Engineering, Petroleum. $3 1018448
690 $a 0542
690 $a 0765
690 $a 0794
710 2 $a Arizona State University. $3 1017445
773 0 $t Dissertation Abstracts International $g 70-04B.
790 $a 0010
791 $a Ph.D.
792 $a 2009
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=3353882