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Ecological Determinants and Effects of Manganese Oxidation State and Bioavailability.

Record Type:	Electronic resources : Monograph/item
Title/Author:	Ecological Determinants and Effects of Manganese Oxidation State and Bioavailability./
Author:	Paulus, Elizabeth Louise.
Description:	1 online resource (205 pages)
Notes:	Source: Dissertations Abstracts International, Volume: 85-03, Section: B.
Contained By:	Dissertations Abstracts International85-03B.
Subject:	Aqueous solutions. -
Online resource:	http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30561725click for full text (PQDT)
ISBN:	9798380264969

Ecological Determinants and Effects of Manganese Oxidation State and Bioavailability.
Paulus, Elizabeth Louise.

Ecological Determinants and Effects of Manganese Oxidation State and Bioavailability. - 1 online resource (205 pages)

Source: Dissertations Abstracts International, Volume: 85-03, Section: B.

Thesis (Ph.D.)--Stanford University, 2023.

Includes bibliographical references

Soil organic matter (SOM) contains more than three times as much C as the atmosphere does. Even a small tip of the balance between SOM formation and SOM decomposition can have disproportionate effects on CO2 concentrations in the atmosphere, therefore on climate. Manganese (Mn) is a biologically essential redox-active metal that remains a largely unexplored but possibly critical element controlling soil C stocks. As Mn undergoes reduction-oxidation reactions, it assumes a reactive, intermediate oxidation state that can oxidize organic C. The significance of Mn redox cycling to ecosystem C storage remains poorly resolved. I combine field measurements from a rainfall gradient and laboratory experiments to elucidate how rainfall shape Mn redox cycling, how Mn redox cycling interacts with SOM in natural soils, and how foliar Mn versus soil Mn influences grass-litter decomposition. This is the first systematic investigation of rainfall's effect on Mn oxidation state within the rhizosphere and on the role of Mn in grassland C stability. Given the existential threat that climate change poses, we need to understand the soil processes that affect this massive, labile C pool.Rainfall gradients are a powerful tool to evaluate how and where Mn potentiates OM decomposition. In Chapter 2, I determine that rainfall defines patterns in Mn oxidation state and redox cycling along a Hawaiian rainfall gradient. In Chapter 3, I analyze the influence of Mn on soil C stability in situ on a grassland rainfall gradient and in vitrousing an incubation experiment; the results show that Mn bioavailability does not destabilize organic C in a grassland soil. In Chapter 4, I examine the roles of soil Mn versus foliar Mn on grass-litter decomposition on a rainfall gradient and in laboratory incubations; both experiments demonstrate that Mn, whether foliar- or soil-derived, does not control litter decomposition in a grassland. This research can inform models to revise projections on the capacity of soils to sequester C in the face of climate change.

Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2023

Mode of access: World Wide Web

ISBN: 9798380264969Subjects--Topical Terms:

3681511
Aqueous solutions.
Index Terms--Genre/Form:

542853
Electronic books.

Ecological Determinants and Effects of Manganese Oxidation State and Bioavailability.
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100 1 $a Paulus, Elizabeth Louise. $3 3703817
245 1 0 $a Ecological Determinants and Effects of Manganese Oxidation State and Bioavailability.
264 0 $c 2023
300 $a 1 online resource (205 pages)
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500 $a Source: Dissertations Abstracts International, Volume: 85-03, Section: B.
500 $a Advisor: Vitousek, Peter;Casciotti, Karen;Fendorf, Scott;Peay, Kabir;Chadwick, Oliver.
502 $a Thesis (Ph.D.)--Stanford University, 2023.
504 $a Includes bibliographical references
520 $a Soil organic matter (SOM) contains more than three times as much C as the atmosphere does. Even a small tip of the balance between SOM formation and SOM decomposition can have disproportionate effects on CO2 concentrations in the atmosphere, therefore on climate. Manganese (Mn) is a biologically essential redox-active metal that remains a largely unexplored but possibly critical element controlling soil C stocks. As Mn undergoes reduction-oxidation reactions, it assumes a reactive, intermediate oxidation state that can oxidize organic C. The significance of Mn redox cycling to ecosystem C storage remains poorly resolved. I combine field measurements from a rainfall gradient and laboratory experiments to elucidate how rainfall shape Mn redox cycling, how Mn redox cycling interacts with SOM in natural soils, and how foliar Mn versus soil Mn influences grass-litter decomposition. This is the first systematic investigation of rainfall's effect on Mn oxidation state within the rhizosphere and on the role of Mn in grassland C stability. Given the existential threat that climate change poses, we need to understand the soil processes that affect this massive, labile C pool.Rainfall gradients are a powerful tool to evaluate how and where Mn potentiates OM decomposition. In Chapter 2, I determine that rainfall defines patterns in Mn oxidation state and redox cycling along a Hawaiian rainfall gradient. In Chapter 3, I analyze the influence of Mn on soil C stability in situ on a grassland rainfall gradient and in vitrousing an incubation experiment; the results show that Mn bioavailability does not destabilize organic C in a grassland soil. In Chapter 4, I examine the roles of soil Mn versus foliar Mn on grass-litter decomposition on a rainfall gradient and in laboratory incubations; both experiments demonstrate that Mn, whether foliar- or soil-derived, does not control litter decomposition in a grassland. This research can inform models to revise projections on the capacity of soils to sequester C in the face of climate change.
533 $a Electronic reproduction. $b Ann Arbor, Mich. : $c ProQuest, $d 2023
538 $a Mode of access: World Wide Web
650 4 $a Aqueous solutions. $3 3681511
650 4 $a Precipitation. $3 3680799
650 4 $a Photographs. $3 627415
650 4 $a Grasses. $3 524890
650 4 $a Lignin. $3 1097216
650 4 $a Spectrum analysis. $3 520440
650 4 $a Oxidation. $3 714629
650 4 $a Geochemistry. $3 539092
650 4 $a Decomposition. $3 3561186
650 4 $a Statistical significance. $3 3702980
650 4 $a Grasslands. $3 650086
650 4 $a Enzymes. $3 520899
650 4 $a Climate change. $2 bicssc $3 2079509
650 4 $a Bioavailability. $3 875104
650 4 $a Analytical chemistry. $3 3168300
650 4 $a Chemistry. $3 516420
650 4 $a Optics. $3 517925
655 7 $a Electronic books. $2 lcsh $3 542853
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690 $a 0996
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710 2 $a Stanford University. $3 754827
773 0 $t Dissertations Abstracts International $g 85-03B.
856 4 0 $u http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=30561725 $z click for full text (PQDT)