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Improving the Performance of Membrane Electrode Assembly CO2 Electrolyzers.
Record Type:
Electronic resources : Monograph/item
Title/Author:
Improving the Performance of Membrane Electrode Assembly CO2 Electrolyzers./
Author:
Shafaque, Hisan Waleed.
Description:
1 online resource (128 pages)
Notes:
Source: Masters Abstracts International, Volume: 83-02.
Contained By:
Masters Abstracts International83-02.
Subject:
Mechanical engineering. -
Online resource:
http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28315394click for full text (PQDT)
ISBN:
9798522912062
Improving the Performance of Membrane Electrode Assembly CO2 Electrolyzers.
Shafaque, Hisan Waleed.
Improving the Performance of Membrane Electrode Assembly CO2 Electrolyzers.
- 1 online resource (128 pages)
Source: Masters Abstracts International, Volume: 83-02.
Thesis (M.A.S.)--University of Toronto (Canada), 2021.
Includes bibliographical references
Detrimental ohmic and mass transport overvoltages experienced by the membrane electrode assembly (MEA) CO2 electrolyzer pose critical barriers to the transition from lab scale to large scale operation. The operating temperature was found to be a critical parameter for improving the performance as the power density was reduced by up to 35 % when increasing the temperature from 25 °C to 60 °C. At low current densities, increasing temperature also led to a 7 fold reduction in ohmic resistance. At higher current densities, overvoltages were dominated by distinct mass transport limitations at the gas diffusion electrodes. Additionally, a high current density of 755 mA/cm2 was reached by fully humidifying the reactant CO2. The power density was reduced by up to 30 % as a result of a 4-fold decrease in ohmic losses. The findings of this thesis provide valuable insights for achieving higher current densities at low cell voltages for CO2 electrolyzers.
Electronic reproduction.
Ann Arbor, Mich. :
ProQuest,
2023
Mode of access: World Wide Web
ISBN: 9798522912062Subjects--Topical Terms:
649730
Mechanical engineering.
Subjects--Index Terms:
Carbon dioxide electrolyzerIndex Terms--Genre/Form:
542853
Electronic books.
Improving the Performance of Membrane Electrode Assembly CO2 Electrolyzers.
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Improving the Performance of Membrane Electrode Assembly CO2 Electrolyzers.
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Advisor: Bazylak, Aimy.
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Includes bibliographical references
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Detrimental ohmic and mass transport overvoltages experienced by the membrane electrode assembly (MEA) CO2 electrolyzer pose critical barriers to the transition from lab scale to large scale operation. The operating temperature was found to be a critical parameter for improving the performance as the power density was reduced by up to 35 % when increasing the temperature from 25 °C to 60 °C. At low current densities, increasing temperature also led to a 7 fold reduction in ohmic resistance. At higher current densities, overvoltages were dominated by distinct mass transport limitations at the gas diffusion electrodes. Additionally, a high current density of 755 mA/cm2 was reached by fully humidifying the reactant CO2. The power density was reduced by up to 30 % as a result of a 4-fold decrease in ohmic losses. The findings of this thesis provide valuable insights for achieving higher current densities at low cell voltages for CO2 electrolyzers.
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Electronic reproduction.
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Ann Arbor, Mich. :
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ProQuest,
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Mode of access: World Wide Web
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http://pqdd.sinica.edu.tw/twdaoapp/servlet/advanced?query=28315394
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click for full text (PQDT)
based on 0 review(s)
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電子資源
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